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How Does Soap Work?
(Q&A by Aaron Chilcott)

Even though we use soap to remove dirt everyday, do we really understand how it works? Let's say you have a dirty shirt. The dirt on your shirt at the molecular level has a charge opposite to the charge on the shirt fiber. This opposite charge is what makes the dirt stick to the shirt. When you introduce soap and water, the water surrounds the dirt and the fiber. It forms an electrical double layer between the dirt and the fiber. Some water molecules join with the fibers and other water molecules join with the dirt particles. These new molecular structures almost always have similar electrical charges which repel each other. Although water alone has a small cleaning effect, you usually need soap. When soap is introduced, it increases the negative charge on both molecular structures. Since the dirt and the fiber are no longer attracted to each other, they separate and the shirt is clean. That is how soap works.
Source: http://www.cleaninglink.com/Cleaning_Library/how_soap_works.htm