|
www.instituteofscience.com [O] The Weight of Hydrogen Gas (H2). S.H. Shakman A study involving approximately 200 interdiffusing gas-pairs supports a value of 4 for the weight of H2 gas in preference to a value of 2, on a scale of 32 for O2 gas. Table A lists ten illustrative gas-pairs (A-B); observed diffusion coef- ficients (Do)*; calculations (Dc) based on viscosity data and conventionally-appraised molecular weight values*; cal- culations (Dc') based on atomic numbers per equation Dc'= 8.9585sqrt(WAsqrtWB+WBsqrtWA)/WAWB, when gases (A,B) are assigned weight values (WA,WB) equal to double the sums of atomic numbers of component atoms, and 8.9585 adjusts raw calcula- tions relative to the base of .181 for N2-O2; and alternate calculations (Dc") identically derived as are Dc' except that H2 is arbitrarily assigned TABLE A-OBSERVED vs CALCUL- a WA value of 2 (thus WA and WB ATED DIFFUSION COEFFICIENTS values approximate convention- A-B Do Dc Dc' Dc" ally-appraised weight values). H2-N2 .674 .656 .703 1.133 Note that orders of agreement N2-O2 .181 .175 .181-BASE with observed values exhibited N2-CO2 .144 .130 .149 by Dc' values (based on a value H2-CO .651 .661 .703 1.133 of 4 for the weight of H2 rela- CO-N2 .192 .174 .197 tive to 32 for (2) are (a) com- CO-O2 .185 .175 .181 parable to those exhibited by H2-O2 .697 .689 .651 1.053 the less-directly derived Dc O2-CO2 .139 .128 .137 values and (b) preferable to H2-CO2 .550 .544 .545 .885 those exhibited by Dc" values. CO2-CO .137 .128 .149 *HIRSCHFELDER, J.O., CURTISS, C.F., and BIRD, R.B., Molecu- lar Theory of Gases and Liquids (1954), p. 579. (As Newton affirmed,"More is in vain when less will serve.") BOOKS IOS instituteofscience.com - - - - - [1986 AAAS Abstract #212; 1986SHShakmanTxu242823] 1996-8 S. H. Shakman. All rights reserved.
|