Comparison between diagrams. Water(a)
and Dry Ice(b)
Liquids can be fleeting...
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Liquid water exists with its vapor at 1 atm pressure
liquid CO2 only exists above the pressure of 5.11 atm.
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In the lab (1 atm) we see that solid CO2 directly
dissociates into gaseous CO2 without making a liquid at all.
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Liquid CO2 is found in most CO2 fire
extinguishers, but only at a temperature below 31.1 oC, (88
F), where the liquid becomes inditinguishible from the gas.
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Liquid water persists to much higher temperatures, over 300
oC, but only at great pressure (100's of atm).
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Only water has a liquid / solid equibrium curve that has
a negative slope, i.e. it melts when you squeeze it. Water is unique in
its highly structured liquid phase (which is why life grows in water)