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The International School of Panama

General Chemistry

Chapter 4 notes – Part III

Unstable Nuclei and Radioactive Decay

Radioactivity

 Radioactivity was discovered by accident by Antoine Henri Becquerel.

 

http://www.accessexcellence.org/AE/AEC/CC/historical_background.html#becquerel

Radioactivity: The process in which some substances spontaneously emit radiation.

Nuclear Reaction: A reaction that involves changes in an atom’s  nucleus.

 

Chemical Reactions

Nuclear Reactions

The atoms of one or more substances are rearranged.

The nuclei of atoms change.

Only the electrons are given, accepted or shared during chemical reactions. Te particles in the nuclei remain the same.

The number of protons and neutrons change during nuclear reactions.

The identity of the atoms do not change

The identity of the atoms change: atoms of different elements are formed.

The rays and particle emitted by radioactive materials are called radiation.

Why do some atoms emit radiation?

Because their nuclei are unstable.

They gain stability by losing energy. They lose energy by emitting radiation in a spontaneous process called radioactive decay.

Why are some nuclei unstable?

Because they have too many or too few neutrons compared to the amount of protons. Therefore the primary factor in the stability of a nucleus is its ratio of neutrons to protons.

Types of radiation

http://cwx.prenhall.com/bookbind/pubbooks/blb/chapter2/medialib/blb0202.html

 

Tyes of radiation

 
                                Deviated towards the negatively charged plate:

                                Alpha radiation, Made up of alpha particles.

 

Deviated towards the positively charged plate:

Beta radiation, Made up of beta particles.

 

Not deflected by electric of magnetic fields:

Gamma radiation, not made of particles.

Characteristics of alpha, beta and gamma radiat ion

Radiation

Symbol

Mass (amu)

Charge

Alpha

42 He or 42 a

4

2+

Beta

0-1b

1/1837

1-

Gamma

00 g

0

0

 We can express a radioactive decay as a nuclear equation. This type of equation shows the atomic number and mass number of the atoms involved. When balancing or completing nuclear reactions remember that both, atomic number and mass number are conserved.

 Gamma rays usually accompany alpha and beta decays. They are the most energetic of the three types of radiation, the most penetrating and the ones that cause more damage.

 Example 1: Write the alpha decay of Radium-226. What element is formed?

                            22688Ra ---à    ??X   + 42 He  + 00 g

                          226 – 4 = 222

                           88 – 2 = 86 (look for this atomic number in the PT)

The element formed is Radon-222

                            22688Ra ---à    22286Rn   + 42 He  +   00 g

 Example 2: Write the beta decay of Carbon-14. What element is formed? 

                            146C ---à    ??X   + 0-1 b + 00 g                                            14 – 0 = 14

             6 – (-1) = 7 (look for this atomic number in the PT)

The element formed is Nitrogen-14

                             146C ---à    147N   + 0-1 b + 00 g      

 Example 3: Write the alpha decay of Uranium-238. What element is formed?

23892U ---à    ??X   + 42 He  + 00 g

                238 – 4 = 234

                92 – 2 = 90 (look for this atomic number in the PT)

The element formed is Thorium-234   

      23892U ---à    23490Th   + 42 He  + 00 g