MANAGING HAZARDOUS SUBSTANCES
ABD 563
Dangerous Goods (Storage and Handling) Regulations 1989
The regulations provide minimum safety standards to protect the worker, the community and the environment from the effects of fires, explosions and escapes of dangerous goods.
Application (Reg 105)
The regulations do not apply to the storage and handling of :
- medical oxygen (no limit)
- oxygen and acetylene welding sets (up to 10 cubic metres of each gas)
- Flammable liquid (petrol, turpentine, kerosene, etc.) up to 250L provided no container is more than 25 litres.
-other dangerous goods up to 100kg
Generally, all premises which store, handle, transfer, use manufacture or sell dangerous goods are affected by the regulations. Some examples of the types of premises affected by the regulations are:
Structure of the Regulations
The regulations consist of 12 parts:
Part 1 General
This part deals with items such as Objectives (Reg 102), Application (Reg 105), Definitions (Reg 107), etc.
Assessment Factor
Some workplaces are required to be registered, licensed or provide notification. The extent of these requirements depends on the assessment factor calculation.
The assessment factor is a calculation of the risk of the dangerous goods present at a workplace. It is weighted to account for not only quantity but also dangerous goods of great hazard.
Most workplaces will have to calculate an assessment factor to determine their obligations under the regulations. Domestic premises and workplaces with small quantities of dangerous goods will not need to carry out the calculation.
Schedule 2 of the regulations - Method for Determining the Assessment Factor for Dangerous Goods Kept at Premises. (page 168)
Refer to handout "Registration, Notification and Licensing of Premises". (pages 3-7).
Example:
How to calculate an Assessment Factor.
Dangerous Good |
Class |
Subsidiary Risk |
Packaging Group |
Quantity |
Oxygen |
2.2 |
5.1 |
50L |
|
Nitrogen |
2.2 |
23L |
||
Acetic Acid (glacial) |
8 |
3 |
II |
10L |
Acetone |
3 |
II |
20L |
|
Ethanol |
3 |
III |
50L |
|
Lead acetate |
6.1 |
III |
6kg |
|
Ammonia solution |
8 |
III |
20L |
|
Ammonia gas |
2.3 |
8 |
10L |
|
Aluminium powder, uncoated |
4.3 |
II |
5kg |
|
Carbon, activated |
4.2 |
III |
10kg |
|
Batteries, wet, filled with acid |
8 |
III |
80L |
|
Ammonium dichromate |
5.1 |
II |
5kg |
|
Barium cyanide |
6.1 |
I |
10kg |
|
Calcium chlorate |
5.1 |
II |
20kg |
|
Butane |
2.1 |
50L |
Class Activity
1. Calculate the Assessment Factor for the following premises:
Manifest
Metal Work Pty Ltd 22 Smith Street Ironville
Occupier Fred Copper
Date Prepared 6 March 1998
Specialist Advice
Mary Tungsten 123 4567
Steven Cobolt 891 2345
Bulk Dangerous Goods
Tank |
Type and Capacity |
Product Name |
UN No. |
Class |
Hazchem |
Quantity |
Tank A |
Bulk Tank on stand |
Hydrochloric Acid |
1789 |
8 |
2R |
5000 litres |
Tank B |
Bulk Tank on stand |
Trichloroethylene |
1710 |
6.1 |
2Z |
5000 litres |
Packaged Dangerous Goods
Product Name |
Class |
Sub Risk |
Hazchem |
PG |
Avg Quantity |
Maxm Quantity |
Gas Store |
||||||
Acetylene |
2.1 |
2[S]E |
6xG* |
10xG* |
||
Argon |
2.2 |
2[T] |
10xG* |
15xG* |
||
Argoshield |
2.2 |
2[T]E |
10xG* |
15xG* |
||
Oxygen |
2.2 |
5.1 |
2[S] |
6xG* |
10xG* |
|
LPG |
2.1 |
2R |
15xD* |
20xD* |
||
DG Store |
||||||
Acetone |
3 |
2[Y]E |
500 litres |
625 litres |
||
Paints |
3 |
3[Y]E |
II |
200 litres |
250 litres |
|
Paints |
3 |
3[Y] |
III |
150 litres |
200 litres |
|
Turpentine |
3 |
3[Y] |
III |
205 litres |
410 litres |
|
Methylated Spirits |
3 |
2[S]E |
II |
205 litres |
410 litres |
|
Thinners |
3 |
3[Y]E |
II |
205 litres |
410 litres |
|
Epoxy Resin |
3 |
6.1 |
3WE |
I |
410 litres |
615 litres |
MEKP |
5.2 |
2WE |
I |
20 litres |
40 litres |
|
Hydrogen Peroxide |
5.1 |
8 |
2P |
III |
410 litres |
615 litres |
Sodium hydroxide solution |
8 |
2R |
II |
615 litres |
825 litres |
|
Store A |
||||||
Nitric Acid |
8 |
5.1 |
4WE |
I |
410 litres |
615 litres |
Store B |
||||||
Waste Acid |
8 |
2P |
II |
615 litres |
825 litres |
|
Waste Trichloro ethylene |
6.1 |
2Z |
III |
615 litres |
825 litres |
|
Waste Sodium Hydroxide |
8 |
2R |
II |
615 litres |
825 litres |
|
Electro plating |
||||||
Acid Bath 1 |
8 |
2P |
II |
420 litres |
420 litres |
|
Acid Bath 2 |
8 |
2P |
II |
420 litres |
420 litres |
|
Treatment |
||||||
Trichloro ethylene Bath |
6.1 |
2Z |
III |
420 litres |
420 litres |
|
Sodium Hydroxide Bath |
8 |
2R |
II |
420 litres |
420 litres |
|
Pickling Bath (Hydrochloric Acid) |
8 |
2R |
II |
420 litres |
420 litres |
|
Spray Painting |
||||||
Cabinet 1 |
||||||
Paints |
3 |
3[Y]E |
II |
60 litres |
60 litres |
|
Paints |
3 |
3[Y] |
III |
40 litres |
40 litres |
|
Cabinet 2 |
||||||
Acetone |
3 |
2[Y]E |
40 litres |
40 litres |
||
Turpentine |
3 |
3[Y] |
III |
60 litres |
60 litres |
|
Methylated Spirits |
3 |
2[S]E |
II |
40 litres |
40 litres |
|
Thinners |
3 |
3[Y]E |
II |
40 litres |
40 litres |
*G size cylinder = 50L
*D size cylinder = 10L
2. Using the information contained in the handout "Registration, Notification and Licensing of Premises" and the outcome of the assessment factor calculation, determine what obligations the occupier of the premises must meet.
Part 3 Accident Prevention, Planning and Management
Division 1 Placarding of Premises and Safety Signs
Refer handout "Hazard Management" pages 2-7.
Internal Placarding refer to handout "Hazard Management" pages 15 & 16.
Activity
Determine the type of placarding required for the following premises.
Manifest
Metal Work Pty Ltd 22 Smith Street Ironville
Occupier Fred Copper
Date Prepared 6 March 1998
Specialist Advice
Mary Tungsten 123 4567
Steven Cobolt 891 2345
Bulk Dangerous Goods
Tank |
Type and Capacity |
Product Name |
UN No. |
Class |
Hazchem |
Quantity |
Tank A |
Bulk Tank on stand |
Hydrochloric Acid |
1789 |
8 |
2R |
5000 litres |
Tank B |
Bulk Tank on stand |
Trichloroethylene |
1710 |
6.1 |
2Z |
5000 litres |
Packaged Dangerous Goods
Product Name |
Class |
Sub Risk |
Hazchem |
PG |
Avg Quantity |
Maxm Quantity |
Gas Store |
||||||
Acetylene |
2.1 |
2[S]E |
6xG* |
10xG* |
||
Argon |
2.2 |
2[T] |
10xG* |
15xG* |
||
Argoshield |
2.2 |
2[T]E |
10xG* |
15xG* |
||
Oxygen |
2.2 |
5.1 |
2[S] |
6xG* |
10xG* |
|
LPG |
2.1 |
2R |
15xD* |
20xD* |
||
DG Store |
||||||
Acetone |
3 |
2[Y]E |
500 litres |
625 litres |
||
Paints |
3 |
3[Y]E |
II |
200 litres |
250 litres |
|
Paints |
3 |
3[Y] |
III |
150 litres |
200 litres |
|
Turpentine |
3 |
3[Y] |
III |
205 litres |
410 litres |
|
Methylated Spirits |
3 |
2[S]E |
II |
205 litres |
410 litres |
|
Thinners |
3 |
3[Y]E |
II |
205 litres |
410 litres |
|
Epoxy Resin |
3 |
6.1 |
3WE |
I |
410 litres |
615 litres |
MEKP |
5.2 |
2WE |
I |
20 litres |
40 litres |
|
Hydrogen Peroxide |
5.1 |
8 |
2P |
III |
410 litres |
615 litres |
Sodium hydroxide solution |
8 |
2R |
II |
615 litres |
825 litres |
|
Store A |
||||||
Nitric Acid |
8 |
5.1 |
4WE |
I |
410 litres |
615 litres |
Store B |
||||||
Waste Acid |
8 |
2P |
II |
615 litres |
825 litres |
|
Waste Trichloro ethylene |
6.1 |
2Z |
III |
615 litres |
825 litres |
|
Waste Sodium Hydroxide |
8 |
2R |
II |
615 litres |
825 litres |
|
Electro plating |
||||||
Acid Bath 1 |
8 |
2P |
II |
420 litres |
420 litres |
|
Acid Bath 2 |
8 |
2P |
II |
420 litres |
420 litres |
|
Treatment |
||||||
Trichloro ethylene Bath |
6.1 |
2Z |
III |
420 litres |
420 litres |
|
Sodium Hydroxide Bath |
8 |
2R |
II |
420 litres |
420 litres |
|
Pickling Bath (Hydrochloric Acid) |
8 |
2R |
II |
420 litres |
420 litres |
|
Spray Painting |
||||||
Cabinet 1 |
||||||
Paints |
3 |
3[Y]E |
II |
60 litres |
60 litres |
|
Paints |
3 |
3[Y] |
III |
40 litres |
40 litres |
|
Cabinet 2 |
||||||
Acetone |
3 |
2[Y]E |
40 litres |
40 litres |
||
Turpentine |
3 |
3[Y] |
III |
60 litres |
60 litres |
|
Methylated Spirits |
3 |
2[S]E |
II |
40 litres |
40 litres |
|
Thinners |
3 |
3[Y]E |
II |
40 litres |
40 litres |
Division 2 Planning for Emergencies and Information for Fire Authorities
Manifests (Reg 308 & 309) (Schedule 7)
Refer to handout "Hazard Management" pages 9-12.
Plans for Management of Emergencies (Reg 306)
Equipment for Treatment of Leaks and Spills (Reg 307)
Refer to handout "Hazard Management page 13.
Display and Location of Safety Information Board (Reg 312)
If the assessment factor is >100 then the fire authority may require a safety information board.
The safety information board must contain the following:
The safety board must be located where fire authorities request.
Division 3 Fire Protection Measures (Reg 313)
Compliance with fire authority’s requirements, see handout "Hazard Management" pages 14 - 17.
Installation and maintenance of fire protection equipment (Reg 314)
Equipment:
Maintenance of Equipment:
Division 4 - Reporting of Accidents
Section 32 of the Dangerous Goods Act 1985 states that:
A Licensee or a prescribed person shall, without delay, report:
(a) to the nearest fire authority; or
(b) to a police station any fire,
any fire, explosion, spillage, leakage or escape involving dangerous goods in the ownership, possession or control of that licence or person".
Occupiers with an assessment factor of 10 or more must report the type of accident, as defined in reg 316(2). Reportable accidents involving dangerous goods are:
In addition to these the requirements of the Occupational Health and Safety (Incident Notification) Regulations 1997 must be met.
Part 4 - General Requirements for the Design, Construction, Location and Operation of Dangerous Goods Storages
Division 1 Application
Reg 400
Minor Quantities
Table 107 of the regulations (pages 14, 15 & 16) sets out what is considered minor quantities for each class of dangerous goods.
Refer to handout "Storage and Handling of Small Quantities" pages 9 - 12.
The following regulations apply to minor quantities:
Division 2 General Requirements for Storage
In the case of spill or leak of any dangerous goods, an occupier must ensure that the spill is confined within the premises.
As well as meeting the requirements under the Dangerous Goods (Storage and Handling) Regs 1989 an occupier of a laboratory in which dangerous goods are used must comply with the requirements set out in AS 2243 parts 1, 2, 6, 7 and 8.
If a new laboratory is to be constructed then it must be constructed in accordance with AS 2982.
Division 3 Design of Package Storage Areas
Unless otherwise specified, Dangerous Goods in packages must be stored in:
(a) An indoor fire-proof cabinet (up to 250L)
OR
(b) A room or space of type A, B, C or D. See Schedule 12 for details.
put in diagram from regs
Dangerous Goods of Classes or Sub Risk 2.1, 3, 4 or 5 are kept in rooms attached to structures adjoining the premises, boundary, or attached to a building used as a residence, then the maximum aggregate of Dangerous Goods allowed to be held is:
2,000 kg/L if the storage is unsprinklered
5,000 kg/L if the storage is sprinklered
If the common wall is of 4 hour fire resistance and extends to the roof level:
10,000kg/L if un-sprinklered
25,000 kg/L if sprinklered.
This regulation applies principally to "factoryette" type premises. The regulation does not apply where each premises has its own four hour fire rated wall.
Storage racks must be structurally sound, permit ready access and be constructed of materials compatible to the goods being stored.
Offices located inside package stores must comply with the following:
(i) Electrical equipment must be suitable for use in the same hazardous area as the store, unless provision is made to ensure that air from the store does not enter the office. This may be accomplished by pressurising the office or by use of an air-lock.
If the office was built after 1st June 1990:
(ii) Be separated from the rest of the store by walls and roof of at least 1 hour fire resistance.
(iii) Have means of escape other than through the store.
A designated room or space must be provided for:
(i) Keeping packages suspected to be leaking;
(ii) Repackaging the contents of leaking packages;
(iii) Decontaminating goods which have been contaminated with Dangerous Goods.
The room or space must be:
(i) Capable of containing any spill of Dangerous Goods;
(ii) Be located outside any storage area unless a safe distance from any Dangerous Goods can be maintained.
Division 4 Storage of dangerous goods in bulk
An occupier must ensure that every tank used for the storage of Dangerous Goods is located in a spill compound which is:
Single Tank For a single tank the capacity of the compound must be capable of holding at least 100% of the capacity of the tank.
Multiple Tanks If more than one tank is located within the spill compound, then the capacity must be at least equal to the largest tank, plus 10% of the next largest tank.
If a sprinkler system is installed, then the capacity of the compound must be increased by a value equal to the volume output of the sprinklers over 20 minutes.
All tanks, other than demountable or tank containers used for transport, are to be permanently installed on stable foundations.
The compound perimeter walls are to be:
(i) impervious to, and compatible with the goods stored;
(ii) Placed to contain spills from the highest tank;
(ii) Separated from protected works by at least 5m.
Product pumps are to be installed outside the compound, unless elevated above the perimeter height or protected by an approved means which prevents the pump form becoming inoperable or a hazard in case of spillage.
Division 5 Avoidance of Ignition Sources
No smoking, lighters, matches, cigarettes, flames or space heaters within 3m of a room or space where class or sub risk 2.1, 3, 4 or 5 Dangerous Goods are stored, unless work is carried out in accordance with reg 436, which stipulates the precautions to be taken to effect repairs within a hazardous area.
All equipment for use within a hazardous area must comply with AS 3000.
Transfer of any fluids by pumps, decanting, pouring, etc. will generate static electricity. To avoid any problems associated with a build-up of static charge, all tanks, pipe works, transfer systems and process plants must be suitably earthed (ref AS 1020).
Correct operating procedures must be implemented and written instructions provided on how to avoid these problems.
Division 6 - Requirements applying to ancillary equipment
There must be enough lighting for people to easily read all markings, signs, instruments etc. Electrical lighting must be approved and relevant to the area. (ref AS 1680, AS 2236 and AS 3000)
Stringent controls are placed on the type of industrial trucks permitted to be used in hazardous areas. Suffice to say that only APPROVED types may be used in Zone 1 or 2 areas. (ref AS 2430)
NO sparks, NO flame, NO refuelling inside dangerous goods storage areas.
Division 7 - Safe Operating Procedures
Security can be a major problem in many dangerous goods storages, therefore an occupier must ensure against any unauthorised entry to dangerous goods kept at the premises by providing:
(i) 1.8m high security fence; or
(ii) Chain wire mesh covered framework, fully enclosing the dangerous goods area; or
(iii) Secure locks on doors, windows and other openings, or
(iv) Continuous supervision; or
(v) Other approved means.
An occupier must ensure that access and egress routes inside areas, rooms or buildings and all external access routes are kept clear at all times.
Access must be available at all times to fire fighting equipment, manifests, PPE and decontamination material and equipment.
This regulation is considered to be very important and is one which is quite often not observed.
An occupier must ensure that areas within or around the room or space where dangerous goods are stored are kept clear of all vegetation, combustible material or any extraneous material which could enhance fire or cause an access or egress problem.
Interceptors, spill collection compounds, drains etc, must be kept clean.
This is an important regulation which costs virtually nothing to comply with.
All those who work with dangerous goods must be given information and training in:
Identification, properties and potential hazards;
Correct use and proper fit of personal protective equipment;
Correct procedures to be followed relating to storage and handling of dangerous goods; and
Emergency measures to be taken for spills, leaks, fires or explosions.
An occupier must provide suitable personal protective equipment and keep it well maintained.
Employees are required to observe the following:
(i) Safe operating procedures;
(ii) Good housekeeping practices;
(iii) Correct use of personal protective equipment;
(iv) The management of emergencies.
Visitors must also comply with safety instructions, notices and, if necessary, use personal protective equipment.
An occupier must ensure that the following requirements are observed in connection with the handling and conveyance of dangerous goods at the premises.
(1) Dangerous Goods must be conveyed in closed containers, pipelines or conduits constructed to prevent escape, unless they are:
(a) solids which don’t generate dusts;
(b) cryogenic liquids of Class 2.2 kept in approved flasks
(c) handled during a manufacturing process (provided they do not generate vapours or mists).
(2) Packages or containers must not be left open, except for the time necessary for the removal of goods.
(3) Packages or containers must not be opened, except in an area where goods are used, tested or transferred.
(4) Packages must be inspected after being filled or delivered and at regular intervals to ensure detection of leaks or damage.
(5) Packages which are damaged or leaking must be immediately re-packed or made safe.
(6) Spillage and leaks must be cleaned up and disposed of or made safe immediately they are detected.
(7) Packages which are leaking, or suspected of leaking, must not be taken into a storage area (use your decontamination area).
Except where elsewhere stated, a sole or inner package may not be opened inside a package store.
This does not apply to packages opened for testing, inspection or tinting paint for immediate sale, provided it is securely resealed and the opening does not pose a risk to health or safety.
Division 8 - Packaging & Labelling Containers of Dangerous Goods
Any package which is filled with dangerous goods for use, other than at the premises at which it is filled, "must meet the specifications required by the Transport Code".
(1) The containers must be approved for dangerous goods.
(2) Every package must be marked as required by the Code.
If containers are to be used at the premises (not transported), they must be:
(i) Sufficiently strong and durable;
(ii) Compatible with dangerous goods;
(iii) Not be softened or weakened by the contents;
(iv) Marked with:
(a) the correct product name (or UN no. may be used).
(b) class label and sub risk, if applicable.
All labels must be removed or obliterated if a package is cleaned free of dangerous goods.
Division 9 - Inspection, Repair & Maintenance of Plant and Equipment
The occupier is required to institute procedures for a programme of regular inspections of plant and equipment, storage tanks and package stores.
Obviously the inspection of package stores will be visible inspections only to assess condition of walls, roof, floors, bunds, electrical equipment, etc.
Depending on the complexity of the plant and equipment, the inspection could range from visible inspection in the case of batch misusing equipment through to complete shut-down in the case of complex plant.
There is no period specified for the inspections discussed above.
The regulations require that storage tanks be inspected for integrity of the tank and fittings at least every 10 years and that the inspection be done in accordance with AS1940 or other approved methods.
Requirements for Specific Classes of Dangerous Goods and Mixed Storage Parts 5 to 12
Introduction
Parts 5 to 12 of the regulations cover:
(a) Storage of Classes 2, 3, 4, 5, 6, 8 and 9.
(b) Storage of certain individual dangerous goods, e.g. Chlorine, Ammonia, Isocyanides, Hydrogen Peroxide, Pool Chlorine; and
(c) Mixed storage of packaged dangerous goods.
These Parts of the regulations generally apply to all quantities of dangerous goods greater than MINOR QUANTITIES, with some additional provisions for storage of minor quantities.
Storage of Class 2
This Part regulates the storage of all Class 2 dangerous goods (gases), with the exception of LP Gas, which has its own storage regulations. There are 12 Divisions in this part, of which the first details general requirements for all gases, encompassing:
(a) Design of storage tanks and cylinders;
(b) Requirements for cylinder storages;
(c) Specification for transfer points.
Generally cylinders must be stored outside unless:
(a) a building is devoted exclusively to the storage of cylinders; or
(b) storage inside is allowed by Regulation 500 eg. Welding sets, medical use, dispensing of beverages.
Any building used for the storage of cylinders must be ventilated as prescribed in the regulations and provided with explosion venting if flammable gases are involved.
Where cylinders are stored outside they must be:
(a) Stored at ground level or on a platform not more than 2 metres high;
(b) Protected from vehicle damage either by location or by bollards or guard rails;
(c) Protected from being knocked over by securing the cylinders; and
(d) Protected from heat from fire in an adjoining building by screen walls of at least two hours fire-resistance or by a distance of at least 3 metres.
Cylinders of Oxygen and Nitrous Oxide must be separated from flammable gases by at least 3 metres or by a barrier of at least thirty minutes fire-resistance.
The other Divisions cover storage of various types of Class 2 gases and include:
(a) Requirements for Cryogenic Liquids of Classes 2.1, 2.2 and 2.3. Storage of Class 2.1 and 2.3 is to be specifications determined by the Director- General in the particular case. Storage of Class 2.2 cryogenic liquids is to be to Australian Standard 1894, with some variations which are given in the regulations.
(b) Requirements for Storage of Liquefied Gases of Class 2.1, with specific requirements for Ethylene Oxide, Butadiene and Vinyl Chloride. Basically storage tanks are to be located in accordance with AS1596, which is the Australian Standard for the storage of LP Gas.
(c) Very brief requirements for the storage of Liquefied Gases of Class 2.2.
(d) Requirements for Liquefied Poisonous Gases of Class 2.3, including specific details for Chlorine (Australian Standard 2927 with variations) and Ammonia (Australian Standard 2022).
(e) Requirements for the Storage of Compressed Gases in tanks.
(f) Requirements on the Sale and Use of Natural Gas or Nitrous Oxide as a Motor Fuel.
This has placed restrictions on the sale of Nitrous oxide, a substance which has been widely used in the past in modified vehicles used in street drag racing. The regulations require that nitrous oxide may not be sold as motor fuel unless the sale or use (and the vehicle in which it is to be used) has been approved by the Chief Commissioner of Police. Records of sales must be kept.
Storage of Class 3
The regulations specify Australian Standard 1940 as the requirement of storage of Class 3 flammable liquids. Combustible Liquids are also regulated. There are some variations and additions to AS 1940, including a prohibition on tanks being installed inside or under buildings.
AS1940 contains rules for the construction and location of both storage tanks and package stores including:
An interesting addition is a regulation on portable containers for motor fuel. This requirement that Class 3 dangerous goods must not e dispensed into any container except:
(a) a metal container with tight fitting closure; or
(b) a container that complies with AS 2906; or
(c) a fuel container for an engine or vehicle; or
(d) a container approved by the Director-General.
This regulation is aimed at stopping the hazardous practice of filling fuel into unsuitable plastic or glass containers, especially food containers. It does not required metal containers to comply with AS 2906, however it does require plastic containers to comply unless they are approved by the Director-General. Plastic containers complying with an overseas standard fit this category.
Storage of Class 4
This part firstly specifies requirements for the storage of Class 4 dangerous goods in packages, including ventilation, spillage retention and explosion venting if flammable gases or combustible dusts can be generated. There are then 3 sections with specific requirements for the storage and handling of Classes 4.1, 4.2 and 4.3 in packages (Storage of bulk Class 4 is to be in accordance with requirements specified by the Director-General in each case).
The section on storage of Class 4.1 specifies the types of rooms or spaces which may be used and limits to 5,000 kilograms the amount of the most hazardous goods which can be stored in that room or space. There then follows a detailed group of regulations on the storage and handling of NITRO-CELLULOSE, including:
(a) specification for package stores;
(b) separation distances from nitro-cellulose stores;
(c) restrictions on quantities in a store; and
(d) requirements for indoor fireproof cabinets.
The requirements for package stores for Class 4.2 dangerous goods are of a general nature. There are two regulations on specific products; one which gives specifications for tanks for Class 4.2 and the other detailing requirements for the storage of Phosphorus in water.
As well as a small number of additional requirements for package store for Class 4.3 dangerous goods, there are specific requirements given for Calcium Carbide package stores.
Storage of Class 5
Class 5 dangerous goods receive a through coverage as befits their nature. As well as the usual general requirements for package stores, there are prohibitions on the keeping of some Class 5 substances together, namely:
(a) ammonium nitrate and other ammonium salts of Class 5.1 must not be stored in the same room or space as any other dangerous goods of Class 5.1; or
(b) dangerous goods of Class 5.1 must not be stored in the same room or space as dangerous goods of Class 5.2
Dangerous goods of Class 5.1 Packaging Group I receive special treatment, including the requirement that they be stored in a room or space located away from other buildings. Sizes of stacks and separation from other occupancies are also specified. Similar sets of requirements are given for Class 5.1 Packaging Groups II and III.
Pool Chlorine, which is defined in the regulations as granular product only, i.e. excluding sodium hypochlorite (liquid), has its own special requirements.
Dangerous goods of Class 5.2 must be stored in compliance with Australian Standard 2714, with the additional requirement that the maximum quantity of dangerous goods of Class 5.2 Packaging Groups II and III that may be stored in a room or compartment is 1000 kilograms.
Storage of Class 6.1
This section is probably the briefest in the parts of the regulations dealing with storage of individual classes of dangerous goods. The requirements are of a general nature but, in particular, specify rules for storage of Class 6.1 Poisons in proximity to foodstuffs. Location rules for package stores are given.
The storage of:
(a) Class 6.1 in bulk; and
(b) Isocyanates and Diisocyanates are to be as specified by the Director-General for a particular case. The storage of Isocyanates and Diisocyanates will be covered by an Australian Standard currently in preparation.
Storage of Class 8 in Packages
Regulation 1001 requires that personal protection equipment be provided near where the goods are kept.
Packages of Class 8 must be kept at least 5 metres from Class 4.3 or 5 and from inorganic cyanides.
Spill collection must be provided where packages are likely to be opened.
Regulation 1002 requires that Class 8 sub-risk 5.1 be separated by at least 3 metres from other dangerous goods of Class 8.
Incompatible dangerous goods of Class 8 eg. concentrated strong acids and alkalies must be kept in separate spill collection compounds.
Regulation 1003 requires that:
Regulation 1004 details requirements for rooms where packages are filled or opened. Only compatible Class 8 materials must be filled in the same room.
An emergency shut off device must be provided for the filling equipment which is operable from both inside and outside the room.
An in-depth treatment of bulk storage of Class 8 is given, including materials of construction of storage tanks, design codes for tanks and requirements for pipes, valves and fittings on tanks.
Storage of Class 9
This is not an area which requires an exhaustive treatment since most Class 9 dangerous goods are fairly innocuous in nature.
Storage of Different Classes in Packages
This is the final part of the regulations, yet in many ways is one of the most important. Many of the more notable fires involving dangerous goods both in Australian and overseas have occurred in mixed storage warehouses.
The requirements of this Part are to be observed, in addition to the requirements of the foregoing Parts of the regulations. They include:
(a) Prohibition on storing certain dangerous goods together;
(b) Requirements for storing limited quantities of certain Classes together , either in Indoor Fireproof cabinets or in quantities less than 10,000 kilograms or litres;
(c) Requirements for the maintenance of segregation or separation between storages, either by means of free space, fire-rated barriers or completely separate rooms;
(d) Location of mixed storage rooms relevant to public places, other buildings etc.
Due to the increased hazards associated with mixed class storages, it is essential that the storage area be properly designed but, more importantly, it must be meticulously managed to ensure that goods which may react dangerously with one another are adequately separated. Similar care must also be taken with different dangerous goods of the same class (such as acids and alkalis which may be dangerously incompatible).
This section can be divided into three main areas of responsibilities:
(1) Small quantities of mixed class dangerous goods stored in flame-proof cabinets
(2) Medium sized mixed storages up to 10,000 kg.
(3) Large scale mixed storages over 10,000 kg.
Dangerous goods of Classes R, 2.3, 6.2, 7 and explosives are not permitted in a mixed storage. They must be kept alone in separate storage areas.
(1) Small Mixed Storages
Many of the regulations in the preceding sections call for stringent controls on items such as spillage control, avoidance of ignition sources, separation distances to other storages or occupied areas, etc.
In many situations these requirements would make it either highly impractical, or even impossible, for many smaller businesses to comply. The regulations recognise these problems and make allowances for the storage of small quantities of mixed dangerous goods, provided they are kept in the following manner:
(a) Each class of dangerous goods must be stored in separate fire-proof cabinets, except that Classes 3 and 4.1 may be stored together.
(b) Each cabinet must contain no more than 250 kg/L.
(c) Cabinets for nitro-cellulose or dangerous goods of Class 5 must be vented to outside.
(d) The cabinets must be at least 1 m apart.
(e) The cabinets should be located in rooms or spaces constructed of non- combustible material (no other requirements apply to the construction of the building).
(f) Class labels must be displayed on the outside of each cabinet.
(2) Medium Sized Mixed Storages
Quantities ranging from minor storage up to 10,000 kg/L may be stored in the same room or space provided:
(a) They are stored in a room or space as described in Schedule 12.
(b) If liquids are kept, then spill collection compounds must be provided.
(c) No dangerous goods of Class 2 (other than non refillable containers of 2.1 or 2.2.) may be stored in the room.
(d) Different classes must be separated by at least 1m.
Keep in mind also the provisions from previous sections relating to items such as placarding, fire extinguishers, spill treatment, ignition sources, etc.
(3) Large Scale Mixed Storages
If the quantity required to be kept exceeds 10,000 kg/L, then certain restrictions apply to the type of goods permitted to be kept in the storage area. The essence of the general requirements of larger mixed class storages is in Table 1205 of the regulations which is reproduced below.
TYPES OF ISOLATION REQUIRED WHILE STORING CLASSES OF DANGEROUS GOODS TOGETHER INCLUDING PROHIBITIONS
Class |
2.1 |
2.2 |
3 PG I & II |
3 PG III |
4.1 |
4.2 |
4.3 |
5.1 |
5.2 |
6.1 |
8 |
9 |
2.1 |
NA |
NA |
FS |
FS |
FS |
PR |
FS |
PR |
PR |
FS |
FS |
SG |
2.2 |
NA |
NA |
SG |
SG |
SG |
FS |
SG |
SG |
FS |
SG |
SG |
SG |
3 PG I & II |
FS |
SG |
NA |
NA |
FS |
FS |
FS |
PR |
PR |
FS |
SG |
SG |
3 PG III |
FS |
SG |
NA |
NA |
SG |
FS |
FS |
PR |
PR |
FS |
SG |
SG |
4.1 |
FS |
SG |
FS |
SG |
NA |
FS |
FS |
PR |
PR |
FS |
SG |
SG |
4.2 |
PR |
FS |
FS |
FS |
FS |
NA |
FS |
PR |
PR |
FS |
SG |
SG |
4.3 |
FS |
SG |
FS |
FS |
FS |
FS |
NA |
PR |
PR |
FS |
FS |
SG |
5.1 |
PR |
SG |
PR |
PR |
PR |
PR |
PR |
NA |
FS |
FS |
FS |
FS |
5.2 |
PR |
FS |
PR |
PR |
PR |
PR |
PR |
FS |
NA |
PR |
FS |
FS |
6.1 |
FS |
SG |
FS |
FS |
FS |
FS |
FS |
FS |
PR |
NA |
SG |
SG |
8 |
FS |
SG |
SG |
SG |
SG |
SG |
FS |
FS |
FS |
SG |
NA |
SG |
9 |
SG |
SG |
SG |
SG |
SG |
SG |
SG |
FS |
FS |
SG |
SG |
NA |
To use the table, select two of the classes proposed to be kept in the storage area. Locate the first class on the top horizontal line and the second class on the vertical column on the left of the table. Read the code at the intersection of the line and column.
NA means that segregation or separation are not applicable; they may be stored in the same area (unless otherwise specified).
SG means that the Classes may be stored only in a Type A, B or D room and must be segregated from each other by a distance of at least 3m.
FS means the Classes must be stored only a type A, B or D room and must be fire separated. Fire separation may be provided by:
(i) Walls of at least 4 hour fire resistance surrounding the storage area for one of the classes; or
(ii) A separation distance (in the same area) of at least 5 m.
Note: Remember to check parts 5 - 11 to ensure that greater distances or separate storages are not required.
PR means that the two Classes are prohibited in the same storage area and must be stored in separate areas, (one of which must be a type D room) at least 10 metres apart.
Separation Distances
Each storage must be located in accordance with Parts 5 - 11, as appropriate to the specific Class kept OR in accordance with Table 1206 below, whichever provides the greatest distance.
Aggregate quantity of dangerous goods (kg) |
Buildings in which other dangerous goods are stored |
Buildings for the process of manufacture |
Protected works |
Boundary of adjoining property |
Places of public assembly |
Public street |
Not more than 10,000 |
5 |
5 |
8 |
8 |
15 |
3 |
More than 10,000 but not more than 100,000 |
8 |
8 |
12 |
12 |
20 |
5 |
100,000 or more |
15 |
15 |
15 |
15 |
30 |
8 |
Transport Depots
This regulation allows for the short term storage of dangerous goods in transit while attracting substantially reduced storage conditions.
It would be appropriate here to look at the definition of a Transport Depot as given in the regulations:-
"Transport Depot" means an area at premises where dangerous goods are kept temporarily as part of the process of transporting them from one place to another.
This means that the concept can apply not only to a Transport Company premises but to an area at a manufacturing or other plant where goods are kept on a short term basis.
The following conditions apply to Transport Depots:-
These are the main requirements for a Transport Depot. Of course, other parts of the regulations will also apply. These are listed in Division 5 of Part 12 of the Regulations and in the colour brochure produced by YWA.