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Chemical Bonding

Chapter 6 Notes

Introduction to Chemical Bonding

Section 6.1

Chemical Bond - a link between atoms that results from the mutual attraction of their nuclei for e-

Types of Chemical Bonds:

1. Metallic Bond - forms between 2 metals

2. Ionic Bond - results from the attraction between positive and negative ions (metal + nonmetal)

one atom has lost electrons (+)

one atom has gained electrons(-)

3. Covalent Bond - results from the sharing of e- b/w 2 atoms (nonmetal + metal)

H Ÿ + HŸ ---> H:H

Types of Covalent Bonds:

A. Non-polar Covalent Bond - the e- are shared equally by the atoms resulting in a balanced distribution of electrical charge.

ex: H , O

B. Polar covalent bond - the e- are unequally attracted by the atoms resulting in an uneven distribution of charge. Part of the molecule will be + and part-

ex: H O H H

O

Determine whether a bond is ionic or covalent?

See figure 5.19 p.153

1. Subtract the electronegativity of one atom from the electronegativity of the other atom.

CS + F (4.0 - 0.7) = 3.3

2. Refer to the % ionic character on p.162

3. So... Cs + F - ionic bond

What About Polarity?

Non-polar covalent bonds - (e-) are shared equally because 2 atoms have the same electronegativity.

Polar Covalent Bonds - (e-) spend more of their time around one atom.