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Things That Go Bang

Threads - Mythbusters

On  24/6/2006, Adam Selinger posted:

This has been a really fascinating discussion on the list. 'Informal'science education is the area I have been involved with for about 15 years. I just wanted to add two comments:

1. Best 'science' on TV, for me, has to be Myth Busters (Mon 7:30pm SBS). These two guys, and colleagues, go about investigating myths with stringent regard for the science method and a great sense of adventure and passion! A must for all science, technology, maths and design students.

2. For a great technology workshop (someone already mentioned soldering) see www.madlab.org I was so impressed with this
learn-to-solder-and-take-way-your-gadget activity from the Edinburgh International Science Festival that I have helped role it out in Oz. Really quite easy to run yourself (once you have the gear) or book in the 'professionals' (e.g. CSIRO Education).

Stephen Watts replied:

I must watch a different series of Mythbusters...
The other night I was watching them trying to prove some point about a medievial trebuchet and a car engine. I watched the nonsense for about 5 minutes. I thought it would have been far easier to prove the point with a pencil and a piece of paper.

Tamara Kelly responded:

I have seen this program twice while at my sister's place and think it's GREAT.

The whole point is for boys to build things and have a great time blowing things up. It's not JUST about proving or disproving some idea - it's about having, big, technical, go bang, FUN.

Who wants to do it on paper? Most people don't understand the mathematics but they can understand when it is demonstrated. What I hope is that it makes non-science people more interested in science and makes them more skeptical and inclined to give it a go.

have (practical) fun

Cathy Watson added:

I think MythBusters is a fantastic teaching tool. My students watch it for "homework" every week and come back asking about all sorts of science concepts. I then encourage them to work in groups to research the concept in question and to tell me all about it, they can even make their own models in class if they like.

I find it really appeals to them as it is exciting, fast paced and hey...they blow things up!
I believe that if we can encourage students to think scientifically (in any way, shape or form), then we are doing them a favour and then this will encourage them to work things out with pen and paper later.

Justin McGuire commented:

It may have been simple to disprove the myth using a pen and paper, but "Jamie and Adam do algebra" doesn't make for good television. TV is a visual medium and I think the approach Mythbusters takes is very well suited to that medium.

Another thing I like about the show is that they always do the experiment, even if I don't always agree with their methodology.

The downside of relying on a mathematical model is that your results are only as good as your model. A good example is the one where they compared driving with air conditioning on to driving with windows open. They started by feeding data from test drives into a computer model, which showed AC was more efficient. However, when they actually tried driving two similar cars using the same amount of fuel, the one using AC ran out of fuel much earlier than the other one. While I have some issues with the methodology they used in this experiment, it certainly showed there were holes in the computer model.

Suzanne Dunn noted:

It may have been simple to disprove the myth using a pen and paper, but "Jamie and Adam do algebra" doesn't make for good television. TV is a visual medium and I think the approach Mythbusters takes is very well suited to that medium.

Another thing I like about the show is that they always do the experiment, even if I don't always agree with their methodology.

Garry Dalrymple wrote:

On Anna's favourite TV show they had a piece on exploding farmers trousers, apparently, and they were _very_ coy about exactly what the chemical was, the use of a '1930s pesticide in New Zealand' resulted in trousers / overalls exploding into flame.

They demonstrated the effect, they compared the effect with some home made gun cotton (nitro cellulose), black powder and even the Fe/Al Hindenburg coating. The pesticide soaked into cotton cloth visibly burned faster than these.

My question is - what on earth are they talking about? What sort of a chemical like that could make it onto the market in even a third world country like NZ in 1930?

Any suggestions? Could make a haka more interesting!

The downside of relying on a mathematical model is that your results are only as good as your model. A good example is the one where they compared driving with air conditioning on to driving with windows open. They started by feeding data from test drives into a computer model, which showed AC was more efficient. However, when they actually tried driving two similar cars using the same amount of fuel, the one using AC ran out of fuel much earlier than the other one. While I have some issues with the methodology they used in this experiment, it certainly showed there were holes in the computer model.

Peter Macinnis replied:

I think potassium chlorate was used as a weed killer.  Or maybe it was potassium perchlorate -- each is a powerful oxidising agent, though perchlorate is better in any bangs-for-a-buck sense.  JATO units in World War II were asphalt and potassium perchlorate, and those certainly packed a punch.

Older readers may recall that the IRA were said to use bombs that incorporated 'weed killer' -- and the authorities were equally coy about that.  I am fairly sure that the perchlorate was NOT used as a weed killer, though it probably could have been.  I have a vague idea that the other half of the IRA formulation was sugar, which I think it is OK to say, since neither of the oxidising agents is available legally, and people knowing where to get the stuff illegally probably have all the information they need.

Paul Williams answered:

<snip>
My question is - what on earth are they talking about?  What sort of a
chemical like that could make it onto the market in even a third world
country like NZ in 1930?
<snip>

Sodium Chlorate.
Science show 2004 - Interview with James Watson (Massey, N.Z) on this:
http://www.abc.net.au/rn/scienceshow/stories/2004/1264069.htm#

Watson later won an Ig Nobel prize (2005) for:
"The Significance of Mr. Richard Buckley's Exploding Trousers:..."
Abstract (which doesn't mention exploding trousers) :
http://caliber.ucpress.net/doi/abs/10.1525/ah.2004.78.3.346;jsessionid=oX6gNCvtL5L6?cookieSet=1&journalCode=ah
Or:
http://tinyurl.com/y4umqt

Brian Lloyd responded:


On Anna's favourite TV

Great show. It is one of the few reasons for still having a TV set.

show they had a piece on exploding farmers
trousers, apparently, and they were _very_ coy about exactly what the
chemical was,

They didn't want Junior trying this one at home.

the use of a '1930s pesticide in New Zealand' resulted in
trousers / overalls exploding into flame.

They demonstrated the effect, they compared the effect with some home
made gun cotton (nitro cellulose), black powder and even the Fe/Al
Hindenburg coating.  The pesticide soaked into cotton cloth visibly
burned faster than these.

Pretty cool, huh!

My question is - what on earth are they talking about?  What sort of a
chemical like that could make it onto the market in even a third world
country like NZ in 1930?

Any suggestions?  Could make a haka more interesting!

Also,

They had 'tallow' rockets, American civil war technology apparently.
Apply heat and some Nitrogen oxide and you can make greasy  smallgoods in
a rocket casing go 'Whoosh' (Weapons of Meat destruction, Pork rockets
against Al Kaida?).   Very impressive but I didn't catch the details.

They build a compound solid/liquid fuel rocket using a pipe casing,  some candle wax (what we call paraffin here in the US, not kerosene)  for fuel, and liquid nitrous oxide as an oxidizer. The bloody thing  actually worked and flew several hundred feet. The myth was the the  Confederate army built ballistic rockets that traveled about 200KM.  So they proved that using period hardware they could have constructed  a rocket but that they could not have reached 200KM. Myth busted.  They neglected that the idea for the technology wasn't around then.

Still, the rocket was WAY COOL. I probably couldn't get away with  doing that with my elementary science class tho'. <sigh>

Peter Macinnis commented:

By that, you mean the technology for liquid fuel rockets, I assume.  I think Tsiolkovsky may have been the first to come up with that -- he was born in 1857, so you may be right.

There were certainly plenty of solid fuel rockets back then, but they were generally regarded as unreliable.  The Austrians used them a lot, because they had many mountainous parts of their empire where people wanted them out and rockets were lighter than artillery.  The British boats used rockets as close-range "artillery" in landings during the Crimean War, but all were powered by special gunpowder formulations.

We will pass over the unfortunate contretemps at Fort McHenry, where only the bombs ever came close to having an effect.  Likewise Copenhagen, the Battle of Nations at Leipzig and certain skirmishes in the Peninsular War.  All of those used gunpowder rockets.

I think we could probably add that liquid nitrous oxide was a bit rare at the time of the US Civil War -- which Americans, in their self-centred way, persist in calling "the Civil War", as if there were no others.

The launch method used in Edward Everett Hales' _The Brick Moon_ (http://www.gutenberg.org/etext/1633), two water-powered flywheels, might have been used to throw stuff, but I think Hale was a Northerner, considering his given names.  (Yup -- a Bostonian.)

Terry Hyland observed:

 Hi all.I know you don't celebrate Thanksgiving so have you ever heard of beer can turkey? or hair spray rockets. you spray the hair spray in a bottom hole shove potatos in the tubes.Then stand back after you ignite.they fly quite far.this I,m sure of the alcohol content.there meant as pranks.same with the turkey bombs,the go quite far.

Alan Emmerson enquired:

Have we forgotten William Congreve's iron rockets that were used to bombard Boulogne in 1805?

and:

Did the chemical have to be a weed killer? Perhaps it was another sort of agricultural chemical.
The performance of the trousers rather sounds as though they had been soaked in a saltpetre solution. A bit like a fuse.

Incidentally, I was interested to read last week that a compound we employed in schoolboy pranks involving sharp bangs and purple brown stains was being used as some sort of detonant by the nasty buggers. Tricky stuff when dry. I wonder how many have lost hands.

Terry Hyland noted:

have we forgetting the Spanish Amanda--with there less the desirable cannon balls

Peter Macinnis responded:

No, Alan, we had not forgotten it -- or, at least I hadn't.  How could I forget what did not happen?  In the strict sense, Boulogne was never bombarded at all, but there was absolutely no rocket attack on Boulogne or its port and environs in 1805.  One was planned, but then called off because the weather was bad.  You are correct on one point: the
Congreves used later (not in 1805) to attack Boulogne were the same ones used at Copenhagen, Leipzig and Fort McHenry.

I assume you were thinking of the attempt to attack the French fleet at Boulogne in 1806 (October 7-8).  Most of the rockets missed the fleet and hit the town, but Boulogne was not the target.  That being so, it is rather less than precise to speak of bombarding Boulogne.

Equally, there was no rocket attack on Cadiz, though Nelson proposed it, just before Trafalgar, in a letter to Canning of October 1, 1805 -- though the idea was to force the ships sheltering there out of the harbour.  Once Nelson died, Wellesley was able to operate his bias against the Congreves in many spheres.

Nothing was forgotten -- I kept it brief and referred to the salient points only.  That is why I left out Boulogne, the Netherlands, and a few other uses.

Alan Emmerson wrote:

Thanks for the info Peter. Learn something everyday.

On the question of liquid fuel rockets, did Ziolkovski actually produce any hardware?
I thought his contribution was in the mechanics of space flight and that Goddard was the first with the hardware.

Brian Lloyd responded:


By that, you mean the technology for liquid fuel rockets, I assume.

Yes. Solid-fuel rockets have been around for about two millenia. I  was speaking of working, liquid-fuel or compound (liquid/solid fuel)  rockets. Robert Goddard is the first I know of to have constructed a  working liquid-fuel rocket.

I think Tsiolkovsky may have been the first to come up with that --  he was born in 1857, so you may be right.

I wasn't aware that he constructed a working rocket.

I think we could probably add that liquid nitrous oxide was a bit  rare at the time of the US Civil War -- which Americans, in their  self-centred way, persist in calling "the Civil War", as if there  were no others.

I think it mostly has to do with familiarity of terms rather than an  attempt to slight anyone else. The term "the Civil War" has been used  for many generations so it is what naturally rolls off the lips. I  think you are attributing more thought to the action than anyone here  bothers to give it.

Heck, most people here want to call the US of A "America". Whenever I  hear that I wonder about the Canadians, the Mexicans, and the people  of Central and South America. Regardless, I think there is a lot more  "familiar use" than intention in its application.

The launch method used in Edward Everett Hales' _The Brick Moon_  (http://www.gutenberg.org/etext/1633), two water-powered flywheels,  might have been used to throw stuff, but I think Hale was a  Northerner, considering his given names.  (Yup -- a Bostonian.)

Allegiances did not fall strictly on geographic boundaries in that  war. (1861)

and:

Incidentally, I was interested to read last week that a compound we  employed in
schoolboy pranks involving sharp bangs and purple brown stains was  being used as some
sort of detonant by the nasty buggers. Tricky stuff when dry. I  wonder how many have
lost  hands.

Nitrogen tri-iodide (NI3). All you need to do is dump iodine into  ammonia. NI3 is what precipitates out. I think most schoolboys  experiment with that at one time or another. It is so unstable I  would never consider using it as a primer.

Heck, when I was making it I would filter the precipitate from the  liquid using filter paper and then I would lay out the filter paper  to dry. Every evening I would come home to find it had detonated  leaving a stain on the kitchen counter to clean up before my mother  saw it. One day I discovered the problem: the sun would reach my  filter paper and set it off. From then on I dried it in a dark place.

So if something is so unstable that mere sunlight can set it off, it  sure as heck is too unstable for anything but small concentrations  used for fun.

Anthony Morton replied:

That'd be the stuff all right.  But with my pedant's hat on, I have a vague recollection that tri-iodide is univalent, which means the formula is actually N(I3)3.  Wierd stuff indeed.

Gerald Cairns posted:

Reminds me of an incident in Chem 1 at Sydney Uni where one student made a significant quantity NI3 and left it in his cupboard to dry during vacation. The inevitable happened and it was fortunate that only a chem lab bench was destroyed.

It wasn't me by the way.

When working with a new refining process in the mid 1980's I did manage unintentionally to create Ag salts in small amounts around the meniscus of the S/S vessel and each time the stirring rod touched the meniscus it would create a small but powerful detonation. It was decided that this process was too unstable to risk scaling up. We did not pursue the identification as explosives were not our aim but Ammonium Ag salts were suspected.

Brian Lloyd responded:

>  It wasn't me by the way. 

Of course not.

When working with a new refining process in the mid 1980's I did  manage
unintentionally to create Ag salts in small amounts around the  meniscus of
the S/S vessel and each time the stirring rod touched the meniscus  it would
create a small but powerful detonation. It was decided that this  process
was too unstable to risk scaling up. We did not pursue the  identification
as explosives were not our aim but Ammonium Ag salts were suspected.

Well, things that explode are "guy" things.

Alan Emmerson commented:

And there was I trying to be discreet about the chemical formulation in case the potentially bad buggers could read..

Gerald Cairns replied:

Not sure which message you are tongue in cheek replying to, mine about AmmoniumAg salts or Ammonium tri iodide but I wouldn't worry too much on that account those substances are so bloody unstable the bad buggers would likely blow themselves up trying to work with them - ionic justice you might say.

 I think they know heaps enough without our contributions so far.


Alan Emmerson answered:

It was the ammonium tri iodide Gerald. The ingredients were in a list of substances recovered from a terrorist group and I was surprised that they seemed to be using it , for just that reason.

Mind you there have been some horrendous accidents with ammonium nitrate too.


Ray Stephens responded:


Ammonium tri iodide 'could' make a detonator for something otherwise more stable.

If it had a point, which it never does outside mining, demolition, road building, or pyrotechnics for entertainment.

Garry Dalrymple wrote:

This sounds a lot like the stuff used in the munitions on Edgar Rice Burroughs' Barsoom (Mars).

They were powered by the 'Eighth Ray' (i.e. a theosophical light/energy beyond the seven colours of the terrestrial rainbow) as was everything else on Barsoom, but on the morning after a battle it was very dangerous to still be on the battlefield as unused or abandoned ammunition detonated when touched by light as the Sun rose.


Gerald Cairns replied:

I seem to recollect that it was painted on the door handles of the car of I think Arthur Calwell NSW Labor Premiere and some others while he was at a function in Mosman many years ago. Apparently someone brushed up against one door and detonated the stuff doing considerable damage to the door handle and maybe someone actually suffered injury too. When the police arrived one officer touched a door handle with his torch and destroyed it.

This is the best of my memory of that fading era. Terrorism ain't new!
Even a fly walking on it can set it off.


Ray Stephens noted:

Picric Acid was one of the substances of choice in WWI munitions, I believe, and this too is also a highly unstable stuff in its dehydrated form.

ftr, it is also used (with extreme care and spillage control) in histology as a tissue stain.