On 12/7/2006 Michael Bailes wrote:
"A US Department of Energy report released on Friday 7 July said that
biofuels such as cellulosic ethanol could displace 30% of the fuel consumed
in US transportation by 2030."
I am sure there would be a lot of N Queensland cane
farmers
<http://forums.hypography.com/#>happy to grow biofuels.
We (& the Poms) already produce a lot of rum in Bundaberg and there is a
lot of bagess left unused.
Some are marketing it as garden mulch.
Morris Gray replied:
Unfortunately the Americans, as usual, are having great difficulty in getting a grasp on reality.
Have look at the U.S. gasoline
consumption of 320,500,000 gallons per day (March 2005) that works out
to about 3700 US gallons or 14,023 litres per second.
By 2030 the US population will
have increased 45% from 280 million to over 400 million. Does anyone
really know how much land and water must be put into supplying biofuels
of this magnitude?
Michael Bailes answered:
Maybe you're right
http://www.nature.com/news/2006/060710/full/060710-4.html
What if we used the woodchips we are sending to Japan?
How does Brazil manage?
Toby Fiander commented:
There is a lot of land which is under used in irrigation terms around NSW.
If the price paid for fuel alcohol is higher enough, then it would be
possible to turn a significant proportion of the available land and water to
alcohol production.
In an average sort of year, assuming 20% of the water is used for fuel
alcohol the following volumes might be made available for production:
Murray (NSW) 140GL
Murrumbidgee 380GL
Macquarie 50GL
All the others 110GL
TOTAL is 680GL/year.
Suppose that 15t/ha of organic matter is available - the crops are largely
irrelevant on this back-of-envelope, but kanaf and hemp spring to mind,
because they can both do better than that. Anyway, assuming 6ML/ha of water
use, then that is 2.5t/ML, or about 1.7Mt/y of organic material. Suppose
dryland production brings this up to 2.5Mt/y of organic material. It is
still not a lot. Suppose it has a little about 10% of sugar or digestible
material to give starch.
Someone with some better expertise than mine might hazard a guess as to the
likely efficiency of alcohol production, but assume for the moment, that
with enough water for the process, which at this scale is an issue, the
alcohol production in NSW from this organic matter could be as much as
300ML/year. This looks small to me...
I have no idea if anyone has tried this before... you would think someone
has, but I don't have time to look just now. Anyone else got any figures?
Alan led an interesting discussion here a while ago about whether there
would be enough nitrogen, phosphorus and potassium and where it might come
from.
Morris Gray responded:
Thanks for your input Toby. Your calculation is very interesting and
probably a bit more considered than any of the powers to be have done.
Here is a web site that gives yields of ethanol and biodiesel per acre from selected crops.
http://gristmill.grist.org/story/2006/2/7/12145/81957
I calculated that using corn, which the Americans have much of:) the
figures are thus: On the daily figure I gave before of their usage of
320,500,000 gallons of gasoline per day would make their yearly usage
116,982,500,000 gallons per year. Assuming that 10% of this was
replaced with ethanol made with corn, that would be 11,698,250,000gal
divided by 354 per acre would make it 33,045,903 acres needed.
Like the Victory Gardens of WWII every household could have their own little patch of corn.
Get you a copper kettle,
Get you a copper coil
Cover with new made corn mash,
and never more you'll toil....
You'll just lay there by the juniper,
While the moon is shining bright
Watch them jugs a fillin' in the pale moonlight....
Peter Macinnis speculated:
I wonder how feasible it would be to track down the gene(s) for breaking
down cellulose that occur in a few organisms.
I think these microbes are found in the gut of both the termite and the
cockroach -- they are certainly in the termite, and aren't there rumen
bacteria in cows that break down cellulose?
What price a yeast that (a) breaks down the cellulose, and (b) ferments
it to alcohol? After you distill off the alcohol (or a goodly part of
it), cool the mash and start the yeasts going again . . . and again . .
. and again . . .
There must be a snag -- it all seems too easy.
Toby Fiander replied:
Yes!
I vaguely remember reading somewhere quite recently that someone was working
on crops whose straw degraded to alcohol as soon as it was dead. It was a
research project still and I thought it was an Australian idea. I have been
looking at academic profiles in recent times, but I do not remember where it
was.
The rumen bacteria are a good start, but you need a digestor and then a
fermenter to go on that journey, whereas single vessel would be required in
theory for something that degraded to alcohol as soon as it was dead.
What price a yeast that (a) breaks down the cellulose, and (b) ferments it
to alcohol? After you distill off the alcohol (or a goodly part of it),
cool the mash and start the yeasts going again . . . and again . . . and
again . . .
Yeah... like that... one vessel.
Of course, if cattle were to eat the degrading straw, that might have some
interesting side effects.
Peter Macinnis responded:
I sent a BCC of my message to Duncan, my younger son, who is working on
(beer) yeasts, and I had this reply, which he says is OK to pass on:
There is a lot of research being done into this. A
group downstairs are doing this, but in zymomonas
mobilis rather than yeast. You'd be able to find
heaps of info on it around and about the place. There
are also people wanting to use waste paper as a carbon
source and so on. Its still slightly more expensive
than processing oil though. Using thermostable
bacteria means you can run the process at 70C and
distill the ethanol straight off. Giving them the
ability to use pentose and hexose sugars is also
important apparently, a friend of mine is doing his PhD in this kind of stuff.
It's great when you can get the kids to do your homework for you!
Morris Gray noted:
If I remember right from my sourdough bread making days one of the
major bye-bye products of fermentation is carbon dioxide. Has anyone
calculated how much CO2 per litre/gal is generated?
The multitude of cooperative little beasties have yet to be exploited,
yet I can't get it out of my mind you can't get something for nothing.
While few people would argue that perpetual motion machines are
possible they happily continue to believe that we can get more out of
nature than we put in. Unfortunately the vast number of parameters that
have to be considered are far beyond the mental age 15 that most
publications aim at.
For example, a recent survey found that most of those surveyed refused
to believe that nuclear reactors in power plants did nothing but boil
water for the steam engines that ran the generators. When the
researchers (falsely) admitted that nuclear reactors generated
electricity directly they were satisfied.
So while the average citizen is considered a 15 year old male both for
science understanding and movie revenue we have no hope other than
knowing......we're all going to die!
Toby Fiander answered:
Probably, but unless I have missed the point here, this carbon is taken by
plants from the atmosphere.
I have always thought it was highly desirable to get something for nothing.
For example, I bought lotto tickets again this week. If I win, you are not
going to know, no one is.
But, as I understand it - and I may not - photosynthetic processes are not
particularly efficient collectors of solar energy, but there is no real
competition.
Morris Gray retorted:
On 13 Jul 2006 at 20:48, Toby Fiander wrote:
> Probably, but unless I have missed the point here, this carbon is
> taken by plants from the atmosphere.
When God designed the conservation
of carbon dioxide I doubt seriously that he contemplated that anyone of
his creatures would plant and ferment 33 million acres of another one
of his creatures to create the Sodom and Gomorrahish mind altering drug
alcohol, either to pour down his 'cake hole' or into the fundamental
orifice of an SUV
> I have always thought it was highly desirable to get something for
> nothing. For example, I bought lotto tickets again this week. If I
> win, you are not going to know, no one is.
I wouldn't tell anyone either if I
won. Unfortunately your belief that you could win is falling in with
the belief in the Law of Infinitesimals vs. Unbelievable Rewards. This
Law states even though one knows the chances of winning are impossible
the rewards, in comparison to the investment, should one win
(impossible though it be) , would offset the investment. Of couse this
is true, were it true.
> But, as I understand it - and I may not - photosynthetic processes are
> not particularly efficient collectors of solar energy, but there is
> no real competition.
Photosynthetic processes can hardly be considered inefficient considering they are responsible for all life on earth.
While you, as man, can revel in your
intelligent efficiency of killing that life, and as rotting vegetation
and blood and bone litter the country side, you can start counting your
ill-gotten gains of winning an impossible game of chance fostered on
your inmature mind of an abstract value system called money.
Money which you seldom see these
days, have no idea how to describe it, and yet should it be plucked out
of your life, would cause great distress to your materialistic world
view.
I admire your tenacity at clinging to lost causes when you know....
we're all going to die!
Michael Bailes wrote:
Cellulose can also be used for biomass
The trees we send to Japan are not irrigated.
See
http://www.iht.com/articles/2006/03/26/business/biofuel.php
If people of the calibre of Branson and Vinod Khosla are putting their $s
behind it their just might be something in it.
Also if we use the biomass to produce low temp. charcoal as a by product
and add this to farm soil we can reduce water use by 17% or more and farm
fertiliser use (often from oil) by up to 50%
and:
Good plans for a backyard energy system using waste or wood to produce
biogas and charcoal
*
http://www.energy.gatech.edu/presentations/dday.pdf
Alan Emmerson added:
Some one remind me please. Don't the organisms responsible for
fermentation actually grow/reproduce/generally-become-more-of in
consequence of their activity?
This may be ok with a ginger beer plant but what do you do with the
mass of organism you finish up with after producing gigalitres of
alcohol..
and:
When a hydrocarbon is oxidised, burned as a fuel say, the products are heat, water and CO
2.
eg 2C
8H
18 +25O
2 = 16CO
2 +18H
2O +4million? BTU
ie 0.23kg petrol + 560 litres oxygen = 360litres CO
2 + 400 litres water vapour
It is fashionable to worry about the CO2 entering the atmosphere, but what about the water?
What about the nearly irreversible loss of atmospheric oxygen that
becomes bound to carbon and hydrogen? No matter what the process, every
kg of CO
2 that is produced ties up 500litres of oxygen and every two litres of water vapour consumes a litre of oxygen in its creation.
Is no one worried about that?
Toby Fiander responded:
I have wondered about this previously.
Photosynthesis is capable of breaking the bond with oxygen. The largest
oxygen production is thought to be from marine phytoplankton, although I
just looked for evidence of this and I cannot find a single easily
accessible reference.
The worry, then, should be about the viability of this process in the region
where it is possible, which has to be the region where sea water is colder
than 10degrees Celsius and whose surface area is being pushed southward by
global warming.
As to whether this is significant, time will tell. I don't propose to be
here by the time it is significant.
The cause for hope is that an increase in carbon dioxide should increase the
vigour of plants generally, provided there is adequate water. Also, you
would think that increasing water vapour in the atmosphere would also reduce
global warming and also lead to increased rainfall, but may be that is too
simplistic.
Peter Macinnis commented:
This is a negative comment, for reasons that are spelled out.
Nonetheless, I believe the mooted lines of enquiry are well worth pursuing.
Michael Bailes wrote:
Cellulose can also be used for biomass
Not yet, Michael, though people are working on it. See what I posted
earlier.
You may not be aware that there is a certain style of "science
communication" that is no more than PR flackery, and the article you
cite is of this sort. Truth is invariably a casualty, as some Great
Person's wisdom in seeing a bright future is lauded in a very North
Korean way.
We are told that people have made "major gains in reducing the cost of
the enzymes needed to produce ethanol from cellulose" -- that is a
standard ambit claim that really means "it is still ten times as
expensive, but maybe we can get around that if we throw more money at it".
A "major gains" claim is about as valid as "shows promise as a possible
cure for cancer". I apologise for early-morning cynicism, but I get too
many of these weasel pieces over my desk, most of them constructed by
science-ignorant but wily journos from bumf fed to them by people with
an axe to grind.
My grandfather used a hay-burner to get around. It would be nice if we
could return to a hay burner that did not, when in use, strew the
streets with a by-product that is redolent of the aroma of that "news
story".
The trees we send to Japan are not irrigated.
True, but the yield is reduced as a result. If you want to maximise the
biomass, you need to attack the limiting factors, one of which is water.
Of course, without care, phosphorus will soon become THE limiting
factor, as it is in second-generation
_Pinus radiata_ forests. For some
reason, nobody seems to think CO2 supplies will be a limiting factor
:-)
Your comment about the woodchips makes me wonder if anything can be done
with the lignin they contain, which is also a waste product from paper
mills, or was, last time I looked -- I may be out of date there.
Peter Macinnis replied:
I did look at that one, and I just did so again to make sure. There is
not a single mention of cellulose in text of Danny Day's entire 54
pages. The term shows up in a few places in the pictures and diagrams,
but I have no regard for people who produce a fruit salad like that in a
format where you can't rummage.
It looked rather more like idealistic polemic to me, all style and no
substance. I have no idea where it is intended to go, and my time is
too precious to waste trawling through it for possible nuggets.
Recall that Thabo Mbeki learned "on the Web" that HIV did not cause
AIDS, and used that as an excuse to deny AZT to pregnant women. He had
failed to recognise that you need a fully-functioning bs detector when
you go to the Web for information. It also says on the Web that global
warming is a furphy created by scientists so they can get more grant
money (the Crichton hypothesis) and that evolution is a fraud, but some
of the crap is less blatant.
I hold in contempt those "science communications" which set out to make
one particular viewpoint (usually a corporate one) look good -- like
much of the stuff favoured by CSIRO management. The pdf you cite may or
may not be such a piece, but I also hold in contempt the confused-babble
style of "science communication", and the pdf you cite is undoubtedly
confused. Perhaps it was better on the day, with somebody to take an
audience through it, but in the absence of that support, it is just a
waste of storage space.
Neither form actually communicates any science or anything about science.
The fact remains that cellulose is not, at present, able to be digested
economically into material that can be converted to energy, and I
suspect that using lignin is even further away, though I seem to recall
learning many years ago about some slow-growing fungi (Basidiomycetes,
possibly) which can digest lignin. Yup:
http://botit.botany.wisc.edu/toms_fungi/may97.html
Also
http://aem.asm.org/cgi/content/abstract/60/8/2985
http://www.fpl.fs.fed.us/documnts/pdf1984/kirk84a.pdf
which I found by going to
http://scholar.google.com/ and setting the
search string <digest lignin fungus OR fungi> (leave out the angle
brackets). This turned up 998 hits . . . none of them PR crap, one hopes.
Nisaba cackled:
> I sent a BCC of my message to Duncan, my younger son, who is working on
(beer) yeasts,
<falls about laughing>
So it's a family thing then?
(Oh, you were serious...)
Peter Macinnis replied:
Absolutely serious. In my day, the students supported the brewery --
but he has it arranged so that the brewery supports him.
I put it down to my singing my children the song of Charlie Mopps (The
Man Who Invented Beer) at bath-time. They can't use GM yeasts, though,
as no brewer wants the bad press that would come their way from the
Great Unwashed.
Nisaba added:
Some one remind me please. Don't the organisms responsible for
fermentation actually
grow/reproduce/generally-become-more-of in consequence of their activity?
This may be ok with a ginger beer plant but what do you do with the mass
of
organism you finish up with after producing gigalitres of alcohol.
You let them stew in their own juices and let them die of alcoholic
poisoning.
No?
You feed them to your chooks?
No?
Maybe float them in sewage tanks and let them process the septic into the
sceptic?
My uncle, who until his death in 1978 held the chair in linguistics at New
South, had a little group of postgrads that he fondly used to refer to as
his "sceptic tank".
and
It is fashionable to worry about the CO2 entering the atmosphere, but what
about the
water?
Make sure it enters the atmosphere in the vicinity of agricultural or
drought-challenged regions?
Ray Stephens noted:
What price a yeast that (a) breaks down the cellulose, and (b)
ferments it to alcohol? After you distill off the alcohol (or a
goodly part of it), cool the mash and start the yeasts going again .
. . and again . . . and again . . .
There must be a snag -- it all seems too easy.Quoting Peter Macinnis --
G'day Peter and hello all.
I'd rather something was gentically engineered to reduce materials
further than
to burnable hydrocarbon and the carbon oxides which result. Biofuels, after
all, will only reduce carbon dioxide waste production (with a BIG maybe for
that too, considering peripheral processes in cultivation, harvest, transport
and processing) and simply provides some assurance that when the fossil fuels
are gone we've got renewable substitutes for the old hazards.
*shrug* bit like sweeping the crud under the carpet IMO.
Anything biologically or potentially GE-able in the way of going all
the way to
graphite and hydrogen from raw hydrocarbon or carbohydrate matrial?
Probably not, but in a world full of High Hopes, one can dream the most
irrational hopes, and if an ancient biology can make food out of sunshine, CO2
& water, then surely (If we really are as smart as we like to think we are) a
bit of tinkering might make something equally as solar-power efficient to
exhale hydrogen gas from domestic waste?
Biofuel is, so far, IMO merely simple economic desperation against the all too
quick loss of its rich fossilised counterparts.
Hoping we can do better.
Michael Bailes wrote:
So you don't agree with the links I sent?
http://www.abc.net.au/rn/allinthemind/stories/2006/1679087.htm
I thought the Herald article would be easy to read
I am sorry the Conference Poster Research Article was too long for you to read.
You also need broadband to download it. It takes me an age too.
It was mainly on biogass which is what we should be making out of the
woodchips we send to Japan.
This is the relevant bit from the Herald Tribune
http://www.iht.com/articles/2006/03/26/business/biofuel.php
The excitement over ethanol derives from research that has cut the
cost of converting nonfood plant matter like grasses and wood chips
into alcohol. Khosla says such cellulosic ethanol will eventually be
cheaper to produce than either gasoline or corn-derived ethanol.
Can investors whose pockets are not so deep jump into the ethanol
market? Yes, but the risk is large in picking long- term winners among
companies that develop any alternative energy technology. The few
publicly traded companies that focus on ethanol are typically
unprofitable. Pacific Ethanol, for example, has not had a profitable
quarter, Langley said, and will not until at least the fourth quarter,
when its first plant is scheduled to begin production.
Few mutual funds focus on alternative energy companies. "We are not
going to start a dedicated alternative energy fund, period," said
Wenhua Zhang, a technology analyst at T. Rowe Price. The company is
avoiding the sector "for the same reason we didn't start an Internet
fund in 2000: a dedicated, very narrow sector fund with a single focus
typically has a much higher risk."
Some publicly traded companies with operations linked to ethanol
include Novozymes and Danisco, both based in Denmark, and Diversa of
San Diego; all three have said they have made major gains in reducing
the cost of the enzymes needed to produce ethanol from cellulose.
Bigger, more diversified companies like Archer Daniels Midland and
Monsanto have ethanol operations, too, though ethanol is but one of
many businesses for these giants.
Two mutual funds that focus on alternative energy include some ethanol
companies among their holdings. The New Alternatives fund holds shares
of Abengoa and Acciona Energía, two Spanish companies investing in
ethanol production. The PowerShares WilderHill Clean Energy Portfolio,
an exchange-traded fund that tracks a basket of 40 alternative energy
companies, includes two companies with significant ethanol interests:
Pacific Ethanol and MGP Ingredients, an ethanol producer in Atchison,
Kansas, according to Robert Wilder, who created the index on which the
fund is based.
Wilder said he expected to add other companies involved with ethanol.
"It's very elegant," he said. "We can take an agricultural waste
product we currently pay to get rid of and convert it into fuel."
"Ethanol is cheaper to produce, unsubsidized, than gasoline today," he
said. "As these technologies ramp up, they will be cheaper,
unsubsidized, than gasoline even if petroleum drops to $35 a barrel."