Site hosted by Angelfire.com: Build your free website today!

<< home  < Articles

Oil Biofuels

Threads - Oil Biofuels
See also Oil From Coal

On 12/7/2006 Michael Bailes wrote:

"A US Department of Energy report released on Friday 7 July said that biofuels such as cellulosic ethanol could displace 30% of the fuel consumed in US transportation by 2030."

I am sure there would be a lot of N Queensland cane farmers<http://forums.hypography.com/#>happy to grow biofuels.  We (& the Poms) already produce a lot of rum in Bundaberg and there is a lot of bagess left unused. Some are marketing it as garden mulch.


Morris Gray replied:

Unfortunately the Americans, as usual, are having great difficulty in getting a grasp on reality.

Have look at the U.S. gasoline consumption of 320,500,000 gallons per day (March 2005) that works out to about 3700 US gallons or 14,023 litres per second.

By 2030 the US population will have increased 45% from 280 million to over 400 million. Does anyone really know how much land and water must be put into supplying biofuels of this magnitude?

Michael Bailes answered:

Maybe you're right
http://www.nature.com/news/2006/060710/full/060710-4.html
What if we used the woodchips we are sending to Japan?
How does Brazil manage?

Toby Fiander commented:

There is a lot of land which is under used in irrigation terms around NSW. If the price paid for fuel alcohol is higher enough, then it would be possible to turn a significant proportion of the available land and water to alcohol production.

In an average sort of year, assuming 20% of the water is used for fuel alcohol the following volumes might be made available for production:
Murray (NSW)  140GL
Murrumbidgee  380GL
Macquarie  50GL
All the others  110GL

TOTAL is 680GL/year.

Suppose that 15t/ha of organic matter is available - the crops are largely irrelevant on this back-of-envelope, but kanaf and hemp spring to mind, because they can both do better than that.  Anyway, assuming 6ML/ha of water use, then that is 2.5t/ML, or about 1.7Mt/y of organic material.  Suppose dryland production brings this up to 2.5Mt/y of organic material.  It is still not a lot.  Suppose it has a little about 10% of sugar or digestible material to give starch.

Someone with some better expertise than mine might hazard a guess as to the likely efficiency of alcohol production, but assume for the moment, that with enough water for the process, which at this scale is an issue, the alcohol production in NSW from this organic matter could be as much as 300ML/year.  This looks small to me...

I have no idea if anyone has tried this before... you would think someone has, but I don't have time to look just now.  Anyone else got any figures?

Alan led an interesting discussion here a while ago about whether there would be enough nitrogen, phosphorus and potassium and where it might come from.

Morris Gray responded:

Thanks for your input Toby. Your calculation is very interesting and probably a bit more considered than any of the powers to be have done.

Here is a web site that gives yields of ethanol and biodiesel per acre from selected crops.

http://gristmill.grist.org/story/2006/2/7/12145/81957

I calculated that using corn, which the Americans have much of:) the figures are thus: On the daily figure I gave before of their usage of 320,500,000 gallons of gasoline per day would make their yearly usage 116,982,500,000 gallons per year. Assuming that 10% of this was replaced with ethanol made with corn, that would be 11,698,250,000gal divided by 354 per acre would make it 33,045,903 acres needed.

Like the Victory Gardens of WWII every household could have their own little patch of corn.

Get you a copper kettle,
Get you a copper coil
Cover with new made corn mash,
and never more you'll toil....

You'll just lay there by the juniper,
While the moon is shining bright
Watch them jugs a fillin' in the pale moonlight....

Peter Macinnis speculated:

I wonder how feasible it would be to track down the gene(s) for breaking down cellulose that occur in a few organisms.

I think these microbes are found in the gut of both the termite and the cockroach -- they are certainly in the termite, and aren't there rumen bacteria in cows that break down cellulose?

What price a yeast that (a) breaks down the cellulose, and (b) ferments it to alcohol?  After you distill off the alcohol (or a goodly part of it), cool the mash and start the yeasts going again . . . and again . . . and again . . .

There must be a snag -- it all seems too easy.


Toby Fiander replied:

Yes!

I vaguely remember reading somewhere quite recently that someone was working on crops whose straw degraded to alcohol as soon as it was dead.  It was a research project still and I thought it was an Australian idea.  I have been looking at academic profiles in recent times, but I do not remember where it was.

The rumen bacteria are a good start, but you need a digestor and then a fermenter to go on that journey, whereas single vessel would be required in theory for something that degraded to alcohol as soon as it was dead.

What price a yeast that (a) breaks down the cellulose, and (b) ferments it to alcohol?  After you distill off the alcohol (or a goodly part of it), cool the mash and start the yeasts going again . . . and again . . . and again . . .

Yeah... like that... one vessel.

Of course, if cattle were to eat the degrading straw, that might have some interesting side effects.

Peter Macinnis responded:

I sent a BCC of my message to Duncan, my younger son, who is working on (beer) yeasts, and I had this reply, which he says is OK to pass on:

There is a lot of research being done into this.  A group downstairs are doing this, but in zymomonas mobilis rather than yeast.  You'd be able to find heaps of info on it around and about the place.  There are also people wanting to use waste paper as a carbon source and so on.  Its still slightly more expensive than processing oil though.  Using thermostable bacteria means you can run the process at 70C and distill the ethanol straight off.  Giving them the ability to use pentose and hexose sugars is also important apparently, a friend of mine is doing his PhD in this kind of stuff.

It's great when you can get the kids to do your homework for you!


Morris Gray noted:

If I remember right from my sourdough bread making days one of the major bye-bye products of fermentation is carbon dioxide. Has anyone calculated how much CO2 per litre/gal is generated?

The multitude of cooperative little beasties have yet to be exploited, yet I can't get it out of my mind you can't get something for nothing.

While few people would argue that perpetual motion machines are possible they happily continue to believe that we can get more out of nature than we put in. Unfortunately the vast number of parameters that have to be considered are far beyond the mental age 15 that most publications aim at.

For example, a recent survey found that most of those surveyed refused to believe that nuclear reactors in power plants did nothing but boil water for the steam engines that ran the generators. When the researchers (falsely) admitted that nuclear reactors generated electricity directly they were satisfied.

So while the average citizen is considered a 15 year old male both for science understanding and movie revenue we have no hope other than knowing......we're all going to die!

Toby Fiander answered:

Probably, but unless I have missed the point here, this carbon is taken by plants from the atmosphere.

I have always thought it was highly desirable to get something for nothing. For example, I bought lotto tickets again this week.  If I win, you are not going to know, no one is.

But, as I understand it - and I may not - photosynthetic processes are not particularly efficient collectors of solar energy, but there is no real competition.

Morris Gray retorted:

On 13 Jul 2006 at 20:48, Toby Fiander wrote:

> Probably, but unless I have missed the point here, this carbon is
> taken by plants from the atmosphere.

When God designed the conservation of carbon dioxide I doubt seriously that he contemplated that anyone of his creatures would plant and ferment 33 million acres of another one of his creatures to create the Sodom and Gomorrahish mind altering drug alcohol, either to pour down his 'cake hole' or into the fundamental orifice of an SUV

> I have always thought it was highly desirable to get something for
> nothing. For example, I bought lotto tickets again this week. If I
> win, you are not going to know, no one is.

I wouldn't tell anyone either if I won. Unfortunately your belief that you could win is falling in with the belief in the Law of Infinitesimals vs. Unbelievable Rewards. This Law states even though one knows the chances of winning are impossible the rewards, in comparison to the investment, should one win (impossible though it be) , would offset the investment. Of couse this is true, were it true.

> But, as I understand it - and I may not - photosynthetic processes are
> not particularly efficient collectors of solar energy, but there is
> no real competition.

Photosynthetic processes can hardly be considered inefficient considering they are responsible for all life on earth.

While you, as man, can revel in your intelligent efficiency of killing that life, and as rotting vegetation and blood and bone litter the country side, you can start counting your ill-gotten gains of winning an impossible game of chance fostered on your inmature mind of an abstract value system called money.

Money which you seldom see these days, have no idea how to describe it, and yet should it be plucked out of your life, would cause great distress to your materialistic world view.

I admire your tenacity at clinging to lost causes when you know....
we're all going to die!

Michael Bailes wrote:

Cellulose can also be used for biomass The trees we send to Japan are not irrigated.
See
http://www.iht.com/articles/2006/03/26/business/biofuel.php
If people of the calibre of Branson and  Vinod Khosla are putting their $s  behind it their just might be something in it.

Also if we use the biomass to produce  low temp. charcoal as a by product  and add this to farm soil we can reduce water use  by 17% or more and farm fertiliser  use (often from oil) by up to 50%

and:

Good plans for a backyard energy system using waste or wood to produce biogas and charcoal

*
http://www.energy.gatech.edu/presentations/dday.pdf

Alan Emmerson added:

Some one remind me please. Don't the organisms responsible for fermentation actually grow/reproduce/generally-become-more-of in consequence of their activity?

This may be ok with a ginger beer plant but what do you do with the mass of organism you finish up with after producing gigalitres of alcohol..

and:

When a hydrocarbon is oxidised, burned as a fuel say, the products are heat, water and CO2.

eg 2C8H18 +25O2 = 16CO2 +18H2O +4million? BTU

ie 0.23kg petrol + 560 litres oxygen = 360litres CO2 + 400 litres water vapour

It is fashionable to worry about the CO2 entering the atmosphere, but what about the water?

What about the nearly irreversible loss of atmospheric oxygen that becomes bound to carbon and hydrogen? No matter what the process, every kg of CO2 that is produced ties up 500litres of oxygen and every two litres of water vapour consumes a litre of oxygen in its creation.

Is no one worried about that?

Toby Fiander responded:

I have wondered about this previously.

Photosynthesis is capable of breaking the bond with oxygen.  The largest oxygen production is thought to be from marine phytoplankton, although I just looked for evidence of this and I cannot find a single easily accessible reference.

The worry, then, should be about the viability of this process in the region where it is possible, which has to be the region where sea water is colder than 10degrees Celsius and whose surface area is being pushed southward by global warming.

As to whether this is significant, time will tell.  I don't propose to be here by the time it is significant.

The cause for hope is that an increase in carbon dioxide should increase the vigour of plants generally, provided there is adequate water.  Also, you would think that increasing water vapour in the atmosphere would also reduce global warming and also lead to increased rainfall, but may be that is too simplistic.

Peter Macinnis commented:

This is a negative comment, for reasons that are spelled out. Nonetheless, I believe the mooted lines of enquiry are well worth pursuing.

Michael Bailes wrote:
Cellulose can also be used for biomass

Not yet, Michael, though people are working on it.  See what I posted earlier.

You may not be aware that there is a certain style of "science communication" that is no more than PR flackery, and the article you cite is of this sort.  Truth is invariably a casualty, as some Great Person's wisdom in seeing a bright future is lauded in a very North Korean way.

We are told that people have made "major gains in reducing the cost of the enzymes needed to produce ethanol from cellulose" -- that is a standard ambit claim that really means "it is still ten times as expensive, but maybe we can get around that if we throw more money at it".

A "major gains" claim is about as valid as "shows promise as a possible cure for cancer".  I apologise for early-morning cynicism, but I get too many of these weasel pieces over my desk, most of them constructed by science-ignorant but wily journos from bumf fed to them by people with an axe to grind.

My grandfather used a hay-burner to get around.  It would be nice if we could return to a hay burner that did not, when in use, strew the streets with a by-product that is redolent of the aroma of that "news story".

The trees we send to Japan are not irrigated.

True, but the yield is reduced as a result.  If you want to maximise the biomass, you need to attack the limiting factors, one of which is water.  Of course, without care, phosphorus will soon become THE limiting factor, as it is in second-generation _Pinus radiata_ forests.  For some reason, nobody seems to think CO2 supplies will be a limiting factor :-)

Your comment about the woodchips makes me wonder if anything can be done with the lignin they contain, which is also a waste product from paper mills, or was, last time I looked -- I may be out of date there.

Michael Bailes repeated:

Did you check the links I posted?
including:
*
http://www.energy.gatech.edu/presentations/dday.pdf

Peter Macinnis replied:

I did look at that one, and I just did so again to make sure.  There is not a single mention of cellulose in text of Danny Day's entire 54 pages.  The term shows up in a few places in the pictures and diagrams, but I have no regard for people who produce a fruit salad like that in a format where you can't rummage.

It looked rather more like idealistic polemic to me, all style and no substance.  I have no idea where it is intended to go, and my time is too precious to waste trawling through it for possible nuggets.

Recall that Thabo Mbeki learned "on the Web" that HIV did not cause AIDS, and used that as an excuse to deny AZT to pregnant women.  He had failed to recognise that you need a fully-functioning bs detector when you go to the Web for information.  It also says on the Web that global warming is a furphy created by scientists so they can get more grant money (the Crichton hypothesis) and that evolution is a fraud, but some of the crap is less blatant.

I hold in contempt those "science communications" which set out to make one particular viewpoint (usually a corporate one) look good -- like much of the stuff favoured by CSIRO management.  The pdf you cite may or may not be such a piece, but I also hold in contempt the confused-babble style of "science communication", and the pdf you cite is undoubtedly confused.  Perhaps it was better on the day, with somebody to take an audience through it, but in the absence of that support, it is just a waste of storage space.

Neither form actually communicates any science or anything about science.

The fact remains that cellulose is not, at present, able to be digested economically into material that can be converted to energy, and I suspect that using lignin is even further away, though I seem to recall learning many years ago about some slow-growing fungi (Basidiomycetes, possibly) which can digest lignin.  Yup: http://botit.botany.wisc.edu/toms_fungi/may97.html

Also
http://aem.asm.org/cgi/content/abstract/60/8/2985
http://www.fpl.fs.fed.us/documnts/pdf1984/kirk84a.pdf


which I found by going to http://scholar.google.com/ and setting the search string <digest lignin fungus OR fungi> (leave out the angle brackets).  This turned up 998 hits . . . none of them PR crap, one hopes.

Nisaba cackled:


        > I sent a BCC of my message to Duncan, my younger son, who is working on (beer) yeasts,

<falls about laughing>

So it's a family thing then?

(Oh, you were serious...)

Peter Macinnis replied:

Absolutely serious.  In my day, the students supported the brewery -- but he has it arranged so that the brewery supports him.

I put it down to my singing my children the song of Charlie Mopps (The Man Who Invented Beer) at bath-time.  They can't use GM yeasts, though, as no brewer wants the bad press that would come their way from the Great Unwashed.

Nisaba added:



Some one remind me please.  Don't the organisms responsible for fermentation actually
grow/reproduce/generally-become-more-of  in consequence of their activity?

This may be ok with a  ginger beer plant but what  do you do with the  mass of
organism you finish up with after producing gigalitres of alcohol.

You let them stew in their own juices and let them die of alcoholic poisoning.

No?

You feed them to your chooks?

No?

Maybe float them in sewage tanks and let them process the septic into the sceptic?

My uncle, who until his death in 1978 held the chair in linguistics at New South, had a little group of postgrads that he fondly used to refer to as his "sceptic tank".
 
and


        It is fashionable to worry about the  CO2 entering the atmosphere, but what about the water?

Make sure it enters the atmosphere in the vicinity of agricultural or drought-challenged regions?

Ray Stephens noted:

What price a yeast that (a) breaks down the cellulose, and (b) ferments it to alcohol? After you distill off the alcohol (or a goodly part of it), cool the mash and start the yeasts going again . . . and again . . . and again . . .

There must be a snag -- it all seems too easy.Quoting Peter Macinnis  --

G'day Peter and hello all.

I'd rather something was gentically engineered to reduce materials further than to burnable hydrocarbon and the carbon oxides which result.  Biofuels, after all, will only reduce carbon dioxide waste production (with a BIG maybe for that too, considering peripheral processes in cultivation, harvest, transport and processing) and simply provides some assurance that when the fossil fuels are gone we've got renewable substitutes for the old hazards.

*shrug* bit like sweeping the crud under the carpet IMO.

Anything biologically or potentially GE-able in the way of going all the way to graphite and hydrogen from raw hydrocarbon or carbohydrate matrial?

Probably not, but in a world full of High Hopes, one can dream the most irrational hopes, and if an ancient biology can make food out of sunshine, CO2 & water, then surely (If we really are as smart as we like to think we are) a bit of tinkering might make something equally as solar-power efficient to exhale hydrogen gas from domestic waste?

Biofuel is, so far, IMO merely simple economic desperation against the all too quick loss of its rich fossilised counterparts.

Hoping we can do better.

Michael Bailes wrote:

So you don't agree with the links I sent?
http://www.abc.net.au/rn/allinthemind/stories/2006/1679087.htm
I thought the Herald article would be easy to read I am sorry the Conference Poster Research Article was too long for you to read.  You also need broadband to download it.  It takes me an age too.  It was mainly on biogass which is what we should be making out of the woodchips we send to Japan.

This is the relevant bit from the Herald Tribune
http://www.iht.com/articles/2006/03/26/business/biofuel.php

The excitement over ethanol derives from research that has cut the cost of converting nonfood plant matter like grasses and wood chips into alcohol. Khosla says such cellulosic ethanol will eventually be cheaper to produce than either gasoline or corn-derived ethanol.

Can investors whose pockets are not so deep jump into the ethanol market? Yes, but the risk is large in picking long- term winners among companies that develop any alternative energy technology. The few publicly traded companies that focus on ethanol are typically unprofitable. Pacific Ethanol, for example, has not had a profitable quarter, Langley said, and will not until at least the fourth quarter, when its first plant is scheduled to begin production.

Few mutual funds focus on alternative energy companies. "We are not going to start a dedicated alternative energy fund, period," said Wenhua Zhang, a technology analyst at T. Rowe Price. The company is avoiding the sector "for the same reason we didn't start an Internet fund in 2000: a dedicated, very narrow sector fund with a single focus typically has a much higher risk."

Some publicly traded companies with operations linked to ethanol include Novozymes and Danisco, both based in Denmark, and Diversa of San Diego; all three have said they have made major gains in reducing the cost of the enzymes needed to produce ethanol from cellulose.

Bigger, more diversified companies like Archer Daniels Midland and Monsanto have ethanol operations, too, though ethanol is but one of many businesses for these giants.

Two mutual funds that focus on alternative energy include some ethanol companies among their holdings. The New Alternatives fund holds shares of Abengoa and Acciona Energía, two Spanish companies investing in ethanol production. The PowerShares WilderHill Clean Energy Portfolio, an exchange-traded fund that tracks a basket of 40 alternative energy companies, includes two companies with significant ethanol interests: Pacific Ethanol and MGP Ingredients, an ethanol producer in Atchison, Kansas, according to Robert Wilder, who created the index on which the fund is based.

Wilder said he expected to add other companies involved with ethanol. "It's very elegant," he said. "We can take an agricultural waste
product we currently pay to get rid of and convert it into fuel."


"Ethanol is cheaper to produce, unsubsidized, than gasoline today," he said. "As these technologies ramp up, they will be cheaper, unsubsidized, than gasoline even if petroleum drops to $35 a barrel."


Rajneesh N Shetty observed:

http://www.fromthewilderness.com/

the above URL has some very interesting information on the "peakoil" concept.

Michael Bailes responded:

No it can be done. We can produce bio-fuels while sequestering large amounts of carbon.
The technology is here now is not difficult, or new, or expensive or potentially dangerous like  a GM solution might be.
See the links I gave

Peter Macinnis answered:

A few simple sums will quickly demolish the fond hope that this strategy will solve our problems: it may help, but it is sadly flawed.

Each of us is responsible for some 27 tonnes of carbon dioxide each year -- that is what our lifestyle generates.  The density of solid carbon dioxide is 1.1 times that of water.  Since it is unlikely to be sequestered as a solid at -57C, we may safely take the density as 1, and that means each person's CO2 occupies a space 3 metres by 3 metres by 3 metres -- about the same volume as a spacious bedroom.

To have any significant impact, we would need to sequester 50% of our national output -- ideally, we would trap the lot, but let's work on 50%.  That means we need to dig 10 holes each year, each 300 metres by 300 metres by 300 metres, and we need to dispose of the material we dig up, and we need to ensure that it stays secure forever.  Not just until it's been through a few half-lives, but forever, and we have to keep on digging the same number, every year -- maybe more.

No earthquake must shift a hole or crack it, no drilling in 10,000 years must break into it, nothing can be allowed to release it.  If it got out of its hole, it would be toxic in the immediate area and when it spread, it would undo all the good that had been done, while we would be left with the carbon debt of digging that hole and removing around 80 million tons of rock in the first place.  That is just one hole, and it will need to be cement-lined, of course, so there's another carbon cost.

In short, the whole proposal won't work.  Neither will the popular idea of growing trees to soak up the CO2 -- the half-life of wood in the bush is of the order of 20 - 30 years, after which it starts to rot, or it is burned in a fire, and in either case, reverts to CO2.

This sort of snake-oil scheme is what happens when economists make policy that relies on market forces to do good!

Michael Bailes retorted:

Nope, still can be done
Google "Terra preta" for starters.
No holes, just digging.

This is interesting too
MARK JACCARD (Perspective: 06/07/2006)
Fossil fuels: friend or foe?
http://www.abc.net.au/rn/perspective/stories/2006/1677566.htm

Toby Fiander replied:

Michael said:

No holes, just digging.

And that is at least part of the point, with a void ratio of 20% say, the space required is increased by a factor of five.  Sequestration is probably doomed before it starts because there just is not enough space anywhere to keep the CO2.

Perhaps you read recently that the CO2 changes the mineralogy of the surrounding strata, in effect dissolving its way out within decades.

At this point most proponents look to the ocean for space.  The risks of sudden  and catastrophic release are high that there will be a boil of some kind if there is a geological disturbance.  The area of the sea bed affected is also considerable, and nothing will live where the CO2 is located.

I could go on, but at best sequestration is a minor measure to try and keep the coal industry working, and with considerable risk.

I have to go and have a good time in the Northern Territory shortly, but sequestration has so many obvious problems that further development is unlikely to fix, you would wonder that anyone would prefer it.

Conventional nuclear energy is much cleaner and less risky - the waste products are small and relatively simply contained compared to CO2.

As the dark Amazonian soil - you are not seriously suggesting this is a way of sequestering carbon are you, Michael?

Steve commented:

Thanks for the URL, specially the 'Dead wrong' is very 'enlightening'. Well balanced, cuts through all kinds of PR
DEAD WRONG: “Too Hot Not to Handle” Dangerous Renewable Energy
Propaganda from the mainstream - by Michael Kane
Paste into Google

Jim Edwards wrote:

Since geosequestration of CO2 looks like being not only too hard but also too dangerous:
http://abc.net.au/science/news/stories/s1683532.htm
is there no way apart from photosynthesis that the two elements can be separated so that only the C needs to be buried (or reused) and the O2 can be released back into the atmosphere?  Or would the energy required generate even more CO2?

Michael Bailes wondered:

There is no point arguing if you don't bother reading the links i give. Are all Ozzie scientists pessimists? It is certainly not the case in the Americas

Conventional nuclear energy is much cleaner and less risky - the waste
products are small and relatively simply contained compared to CO2.
Cleaner than coal yes,( and less radioactive waste being pumped into the atmosphere) but you can't dig a hole deep enough to get rid of the nuclear waste without some life being present. The US and other countries only stopped throwing 44gal drums of plutonium into the sea in 1990

As the dark Amazonian soil - you are not seriously suggesting this is a way
of sequestering carbon are you, Michael?
Yes, the sums have been done. It (alone) may keep us running on the spot, CO2 wise. It can also be a source of biogas and other chemicals we presently get from oil.

I am not convinced yet that the planet is warming in the long term. Certainly the CO2 is a problem in the short term. It is some mother of an experiment we are making with the global ecology. :

Toby Fiander replied:

Michael said:

 It is some mother of an experiment we are making with the global ecology.

At least we agree on this!

As to whether Aussie scientists are pessimists, perhaps it is the competitive funding....  But a realistic appraisal of sequestration could only make it a third order solution.

There is more to be said on the Amazon soil issue, but I am about to go and make a last ditch attempt to get some work done before I leap out the door to go to Kakadu.  May be someone else might like to take it up.

Peter Macinnis noted:

Michael Bailes wrote:
There is no point arguing if you don't bother reading the links i give.

Michael, I can give you links asserting that the world is flat.  Links prove nothing, except that there are rogues and/or fools out there.  I read one of your links -- an incoherent and entirely uninformative, woefully padded farrago of waffle and pie in the sky.

But you are right, there is no point in arguing with you.  Your mind is made up, and you don't want it confused with facts.

Are all Ozzie scientists pessimists?

No, but it is better to be a realistic pessimist than a gullible lemming.  I have spent a goodly part of my life training young people not to be gullible, but you seem to either lack a bs detector, or to have switched it off.

It is certainly not the case in the Americas

Clearly you don't mix very much with American geophysicists, then.

and:

Michael Bailes wrote:


i did post about that
So you don't read my posts either
Fairly pointless conversation.
Michael

I would not be so bold as to classify my attempts to clarify a few simple points as a conversation.  I agree that it is, however, pointless to engage in any palimpsest of a dialogue -- I was only correcting your errors so that others would not be misled by your data-free assertions.

I do, however, await with interest, your practical scheme to capture the world's CO2 output, and turn it into granular carbon, buried in the soil.  Each Australian's carbon output each day is around 20 kg of carbon.  As a block of graphite, that would be about 9 litres, as granular carbon, it will be a great deal more.  A family of three will need to dispose of some 10 cubic metres a year, which will lead to a situation where the back yard will soon be above the eaves.

Jim posed the question: how do you strip out the carbon, to which I would like to add: where do you get the energy to do it?  Burning carbon to make carbon dioxide releases energy, and you need to supply that energy when you reverse the process.


Ray Stephens posted:

It is certainly not the case in the Americas

What isn't?
(sorry, but it is a bit difficult to follow a thread with a few days lapse in reading)

From what I can tell "The Americas" (or anywhere else) don't have sole rights on Earth to either fact or fiction, and are as liable to colouring truth for their own mercenary or political purpases as are anyone else.

It is what we do.
We're born with sufficient self delusion to consider ouselves the centre of the universe, and lies just don't get any bigger than that one.

After all, didn't North America as the USA part of it give Taliban Afghanistan 100s of millions of dollars earlier in 2001 than September 11th before the CIA trained Osama knocked down two of their phallic symbols?  And of course, billions of dollars to Saddam to kill Iranians whilst also providing weapons to Iran (Oliver) to kill Iraqi.

*sigh* Truth is often even strange than fiction, and I doubt very much that "Satan" couldn't interpret the bible to promote a Crusade any better than Enron could falsify its science research as efficiently as its book-keeping.

I also have no doubt that Greenpeace can do the same thing from the other direction, and essentially, if sitting on your hands doesn't work then pontificating probably doesn't work either.

Point is, if you find a silver lining in the clouds it probably just means it is going to rain heavy metals.  Just hope it doesn't rain too much.

and:


Recent research in Australia has found that drought reduces the effectiveness of  forests in sequestering CO2, from 25% or our current output down to 20% of it.

Suggesting a possible global warming rate higher than is currently anticipated.

25% isn't much of a reduction in CO2 by trees (what's left of them), given that some places are generating an excess far higher, and "forestry CO2 credits" are no realistic recompense for damages done.

They're something, better than nothing.

IMO, we people have been getting pretty much a free ride for the last 300 industrially exploitative years and that payment is pending shortly.

There are bills for sacking South America of its argentum & gold and Africa is still a post-imperial "basket case" and every now and then the NRA pays with a Columbine.  Shit happens.  Just try to keep yout mouth above the water.

Peter Macinnis wrote:

John Winckle wrote:
----- Original Message -----
From: "Michael Bailes" <michaelangelica@GMAIL.COM>

The US and other countries only stopped throwing 44gal drums of plutonium
into the sea in 1990

This list is not the place for this sort of politically motivated paranoia!

I suggest that Michael enter a defence of truth and public benefit.

Would it have been less politically motivated or less paranoid if he had named the other countries and/or added that it stopped in 1972 after a convention in London?

I must confess that I had thought it unlikely that anybody was throwing away plutonium, but as far as I can work out, they were dumping waste that contained a fair amount of plutonium.  And the US was the main practitioner, aided by assorted European countries and the USSR.

Oh for the bad old days when you could be given a lump of uranium so you could feel how warm it was . . . or when items like this could appear in print:

"Within a few years isotopes will turn up in many more expected or unexpected places — perhaps the slogan 'Gamma Washes Whiter', will become quite familiar to us when our ultra-sonic washing machines are equipped with some gamma source to sterilize shirts and socks and napkins."

— Egon Larsen, Atomic Energy, Pan Books, 1958, p. 136-7.

or just before it,

"Solid wastes can be disposed of by incineration, closed storage, open burial, or drainage out to sea.  Incineration is especially valuable for treating animal carcases and as a means to reduce the volume of the solid waste, but it gives rise to active gases and ash.  The discharge of the gases should be clear of windows.  Burial may be used on permanently enclosed sites at levels depending on the rainfall so that local groundwater is not contaminated.  Even highly radio-active solid wastes can be disposed of safely in the sea provided all relevant factors are kept in mind: movement of the surface water, the breeding and migratory habits of fish, and the possible hazard to seaweed where it is harvested for food, fertilization, or industrial use."

— Egon Larsen, Atomic Energy, Pan Books, 1958, p. 136.

Some days, I get the feeling that a small amount of paranoia is good for you.


Michael Bailes responded:

Maybe you are right.
I read either in a book by sSuzuki or Byson that nuclear dumping had ended in 1990.(I was surprised by that late date)
But, a quick search on the web shows it seems it is still happening!
Amazing
What has neo-marxistism got to do with it??

"Since 1983 a moratorium on the dumping of low-level radioactive wastes has been in place pending the completion of scientific and technical studies as well as studies on the wider political, legal, economic and social aspects of radioactive waste dumping. Following completion of these studies, the Parties agreed in 1993 to amend the Annexes I and II to the London Convention to ban the dumping of all radioactive wastes. This legally binding prohibition entered into force on 20 February 1994"
FROM
http://www.londonconvention.org/London_Convention.htm#Radioactive%20wastes


"Dumping of highly radioactive wastes at sea has been banned worldwide for more than three decades, still it has been revealed that Russia (the former Soviet Union) has been dumping highly radioactive materials in the Arctic Sea (more precisely the Barents Kara Seas) since the late 1950s."
FROM
http://www.american.edu/TED/arctic.htm

"The ocean is no longer considered as the ultimate dustbin for wastes, and those still carrying out the limited ocean dumping practices that are still allowed are on the defensive and often carry them out with shame. However, land-based discharges and emissions from the nuclear and chemical industries continue and urgently need to be brought to an end."
FROM
http://66.102.7.104/search?q=cache:5UEH6LeT1LYJ:archive.greenpeace.org/odumping/radioactive/reports/odhistory.pdf

and:

Thank you Peter,
I did say "other countries" I was not singeling out the US.
It seems Russia may still be a problem.
As the wit said
"Just because you are paranoid; doesn't mean they are not out to get you."

More on topic re Biofuels
This is a very interesting link.
(Some were sceptical about cellulose being able to be used.)

http://www.rsc.org/chemistryworld/News/2006/July/13070601.asp
Quote:
Catalyst cracks tough cellulose
13 July 2006

Peter Macinnis commented:

Interesting -- but more interesting is one of their references:  here is the abstract and a 'Perspectives' summary about it.  Note that the 'Perspectives' piece says ethanol is NOT the way to go, but alkanes are -- and gives reasons that had never occurred to me.

We still need to discover some hydrogen wells.

Michael Bailes replied;

MMM
Never heard of alkanes

All the carbon bi-products of bio-mass/gas/ethanol power generation are interesting. How are alkanes liquid? and "acid-catalyzed dehydration"? What's that?
and followed by "aldol condensation over solid base catalysts to form large organic compounds" is?

I am not a chemist but it sounds a lot more complex than producing bio-gas, charcoal (to sequester) and ethanol from cellulose. simple systems can be set up in third world countries. Combined with responsible forestry (ie The English example of Coppicing) it may be a simpler solution.

While ethanol may not be the way to go don't you think we need some intermediate technology to keep my car on the road a little longer (than me)

Peter Macinnis answered:

Yes you have -- methane, ethane, propane, octane are all alkanes -- it is just a general term for a class of hydrocarbons, some gaseous, some liquid: larger ones are liquids at room temperature.

The 'Perspectives' article apparently makes it clear that there is an energy loss in going to ethanol that can be avoided by making alkanes instead.  We have the infrastructure in place to work with stuff like that, in the form of oil refineries -- and engines that can use it, as is.

That's why I like it as an idea.

Michael Bailes responded:

Thanks for the explaination.
I like the idea too
So how do we stop people sending woodchips to Japan that we can use for bio-fuels?

Peter Macinnis replied:

I liked a message I saw stencilled on a step near Bondi last summer.  As I recall, it read:  "People don't kill forests.  Gunns do."

Perhaps you saw Media Watch last night.  There is a sneaky rhetoric about jobs and why we have to chip the forests that is used by very clever, very devious people -- a bit like the Shell PR flacks who tried to flog their magic cure for CO2.  Their efforts no doubt pay them well, but they are totally unethical, and they harm our future.

Being the boy who points to the emperor's deficiencies in the wardrobe department is a fairly lonely task: you need to understand the methods without having succumbed to the temptation to go to the Dark Side.  We need more alert minds with enough chutzpah to shout "Oh no, it's not!" at the right times.

What we don't need is more feral greenies chaining themselves to things.  I know the dears have their hearts in the right place, but they don't win hearts and minds where we need them to be won.