Articles about Time Sycronization:
Time adjust in Linux, using ntpdate command; Similar; Using NTPD; File for using NTPD command ; In this link, details about the NTPD command and the files that it uses.
Brazilian Time servers:
ntp.usp.br (USP, Stratum 2, São Paulo, SP); ntp.hiway.com.br (Stratum 2, Valinhos, SP); a.ntp.br, b.ntp.br , c.ntp.br (Oficcial Public Brazilian Timeservers, Stratum 1); ntp.puc-rio.br (PUC, Rio de Janeiro, Stratum 2); ntp.cais.rnp.br (RNP, Brasilia.Stratum 1. other servers in: RNP); ntp.on.br, ntp2.on.br ( Observatório Nacional, Precise standard, Stratum 1); br.pool.ntp.org (Pool of the Official Brazilian Time servers); south-america.pool.ntp.org (South-America Pool of servers).
STRATUM: Stratum 1 servers are those syncronized directly with the standard clock, for example by GPS. To these, are connected secondary servers (very accurate!). Servers of Stratum 3 and Stratum 4 are in general internal servers, and are obsolete for regular public acess or use in time syncronization.
You may see all the time servers in the Oficcial Home-Page of the NTP protocol, and in This page
In windows, is intuitive to Syncronize time, under Linux, use NtpDate ou Better NTPD.